Temperature and Composition Dependence of the Densities, Viscosities, and Speeds of Sound of Binary Liquid Mixtures of 1-Butanol with Hexadecane and Squalane

Temperature and Composition Dependence of the Densities, Viscosities, and Speeds of Sound of Binary Liquid Mixtures of 1-Butanol with Hexadecane and Squalane

Excess molar volumes, V m E, viscosity deviations, Δη, deviations in speed of sound, Δu, and isentropic compressibility, Δκs, for the binary mixtures of 1-butanol, C4H9OH with hexadecane, C16H34, and squalane (2,4,6,10,15,19,23-hexamethylteracosane), C30H62, at T = (298.15, 303.15, and 308.15) K and...

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Veröffentlicht in:Journal of chemical and engineering data 2008-04, Vol.53 (4), p.1032-1038
Hauptverfasser: Dubey, Gyan P, Sharma, Monika
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Chemical thermodynamics
Chemistry
Exact sciences and technology
General and physical chemistry
Mixtures
Thermodynamic properties
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Sharma, Monika
description Excess molar volumes, V m E, viscosity deviations, Δη, deviations in speed of sound, Δu, and isentropic compressibility, Δκs, for the binary mixtures of 1-butanol, C4H9OH with hexadecane, C16H34, and squalane (2,4,6,10,15,19,23-hexamethylteracosane), C30H62, at T = (298.15, 303.15, and 308.15) K and at atmospheric pressure were derived from experimental density, ρ, viscosity, η, and speed of sound, u, data. The calculated excess and deviation functions were further fitted to the polynomial relation to estimate the coefficients and standard errors. The Prigogine−Flory−Patterson (PFP) theory has been used to explain V m E, whereas PFP theory with the van der Waals (vdW) potential energy model has also been used for theoretical estimation of u and κs.
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subjects Chemical thermodynamics
Chemistry
Exact sciences and technology
General and physical chemistry
Mixtures
Thermodynamic properties
title Temperature and Composition Dependence of the Densities, Viscosities, and Speeds of Sound of Binary Liquid Mixtures of 1-Butanol with Hexadecane and Squalane
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