Solubility of Parabens in Subcritical Water
The solubility of methyl, ethyl, and butyl parabens (4-hydroxybenzoate) in water was determined at (298, 373, 423, and 473) K using a homemade heating/mixing system and by high performance liquid chromatography analysis. The solubility increased for all three parabens studied when water temperature...
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Veröffentlicht in: | Journal of chemical and engineering data 2014-03, Vol.59 (3), p.912-916 |
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creator | Kapalavavi, Brahmam Ankney, John Baucom, Matthew Yang, Yu |
description | The solubility of methyl, ethyl, and butyl parabens (4-hydroxybenzoate) in water was determined at (298, 373, 423, and 473) K using a homemade heating/mixing system and by high performance liquid chromatography analysis. The solubility increased for all three parabens studied when water temperature was raised from 298 K to 423 K. However, the solubility decreased with a further temperature increase from 423 K to 473 K. This was due to the degradation of parabens at 473 K as revealed by a separate study. A new model was developed to guide the estimation of paraben solubility in subcritical water. The solubility values predicted using this new model compare reasonably well with our experimental values. |
doi_str_mv | 10.1021/je4010883 |
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The solubility increased for all three parabens studied when water temperature was raised from 298 K to 423 K. However, the solubility decreased with a further temperature increase from 423 K to 473 K. This was due to the degradation of parabens at 473 K as revealed by a separate study. A new model was developed to guide the estimation of paraben solubility in subcritical water. The solubility values predicted using this new model compare reasonably well with our experimental values.</description><identifier>ISSN: 0021-9568</identifier><identifier>EISSN: 1520-5134</identifier><identifier>DOI: 10.1021/je4010883</identifier><language>eng</language><publisher>American Chemical Society</publisher><ispartof>Journal of chemical and engineering data, 2014-03, Vol.59 (3), p.912-916</ispartof><rights>Copyright © 2014 American Chemical Society</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a259t-e5bd24fd832dc0d15a41c9afe285deea6d97e804ac61b77f71c27f2cdd49ab653</citedby><cites>FETCH-LOGICAL-a259t-e5bd24fd832dc0d15a41c9afe285deea6d97e804ac61b77f71c27f2cdd49ab653</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/je4010883$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/je4010883$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,776,780,2752,27053,27901,27902,56713,56763</link.rule.ids></links><search><creatorcontrib>Kapalavavi, Brahmam</creatorcontrib><creatorcontrib>Ankney, John</creatorcontrib><creatorcontrib>Baucom, Matthew</creatorcontrib><creatorcontrib>Yang, Yu</creatorcontrib><title>Solubility of Parabens in Subcritical Water</title><title>Journal of chemical and engineering data</title><addtitle>J. Chem. Eng. Data</addtitle><description>The solubility of methyl, ethyl, and butyl parabens (4-hydroxybenzoate) in water was determined at (298, 373, 423, and 473) K using a homemade heating/mixing system and by high performance liquid chromatography analysis. The solubility increased for all three parabens studied when water temperature was raised from 298 K to 423 K. However, the solubility decreased with a further temperature increase from 423 K to 473 K. This was due to the degradation of parabens at 473 K as revealed by a separate study. A new model was developed to guide the estimation of paraben solubility in subcritical water. 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Chem. Eng. Data</addtitle><date>2014-03-13</date><risdate>2014</risdate><volume>59</volume><issue>3</issue><spage>912</spage><epage>916</epage><pages>912-916</pages><issn>0021-9568</issn><eissn>1520-5134</eissn><abstract>The solubility of methyl, ethyl, and butyl parabens (4-hydroxybenzoate) in water was determined at (298, 373, 423, and 473) K using a homemade heating/mixing system and by high performance liquid chromatography analysis. The solubility increased for all three parabens studied when water temperature was raised from 298 K to 423 K. However, the solubility decreased with a further temperature increase from 423 K to 473 K. This was due to the degradation of parabens at 473 K as revealed by a separate study. A new model was developed to guide the estimation of paraben solubility in subcritical water. The solubility values predicted using this new model compare reasonably well with our experimental values.</abstract><pub>American Chemical Society</pub><doi>10.1021/je4010883</doi><tpages>5</tpages></addata></record> |
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title | Solubility of Parabens in Subcritical Water |
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