Partial Molar Isentropic Compressions and Partial Molar Volumes of Selected Branched Aliphatic Alcohols at Infinite Dilution in Water at Temperatures from T = (278 to 318) K and Atmospheric Pressure
Speed of sound data for dilute aqueous solutions of one monohydric alcohol (2,2-dimethylpropane-1-ol), five polyhydric alcohols (2-methylpropane-1,3-diol, 2,2-dimethylpropane-1,3-diol, 2,2-bis(hydroxymethyl)propane-1-ol, 2,2-bis(hydroxymethyl)propane-1,3-diol, 2,2-bis(hydroxymethyl)butane-1-ol...
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Veröffentlicht in: | Journal of chemical and engineering data 2012-05, Vol.57 (5), p.1570-1580 |
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creator | Šimurka, Lukáš Cibulka, Ivan Hnědkovský, Lubomír |
description | Speed of sound data for dilute aqueous solutions of one monohydric alcohol (2,2-dimethylpropane-1-ol), five polyhydric alcohols (2-methylpropane-1,3-diol, 2,2-dimethylpropane-1,3-diol, 2,2-bis(hydroxymethyl)propane-1-ol, 2,2-bis(hydroxymethyl)propane-1,3-diol, 2,2-bis(hydroxymethyl)butane-1-ol), and one ether alcohol (3,3,7,7-tetrakis(hydroxymethyl)-5-oxanonane) were obtained using the Anton Paar DSA 5000 vibrating-tube densimeter and sound analyzer in the temperature range from (278.15 to 318.15) K and at atmospheric pressure. Standard molar isentropic compressions were evaluated from the measured data. Measured densities of dilute aqueous solutions of 2,2-dimethylpropane-1,3-diol and 2,2-bis(hydroxymethyl)propane-1,3-diol are also presented along with the standard molar volumes of these two solutes calculated from the measured data. Relations between the two standard quantities and molecular structures of the solutes are discussed. |
doi_str_mv | 10.1021/je300175w |
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Standard molar isentropic compressions were evaluated from the measured data. Measured densities of dilute aqueous solutions of 2,2-dimethylpropane-1,3-diol and 2,2-bis(hydroxymethyl)propane-1,3-diol are also presented along with the standard molar volumes of these two solutes calculated from the measured data. 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Chem. Eng. Data</addtitle><description>Speed of sound data for dilute aqueous solutions of one monohydric alcohol (2,2-dimethylpropane-1-ol), five polyhydric alcohols (2-methylpropane-1,3-diol, 2,2-dimethylpropane-1,3-diol, 2,2-bis(hydroxymethyl)propane-1-ol, 2,2-bis(hydroxymethyl)propane-1,3-diol, 2,2-bis(hydroxymethyl)butane-1-ol), and one ether alcohol (3,3,7,7-tetrakis(hydroxymethyl)-5-oxanonane) were obtained using the Anton Paar DSA 5000 vibrating-tube densimeter and sound analyzer in the temperature range from (278.15 to 318.15) K and at atmospheric pressure. Standard molar isentropic compressions were evaluated from the measured data. Measured densities of dilute aqueous solutions of 2,2-dimethylpropane-1,3-diol and 2,2-bis(hydroxymethyl)propane-1,3-diol are also presented along with the standard molar volumes of these two solutes calculated from the measured data. Relations between the two standard quantities and molecular structures of the solutes are discussed.</description><issn>0021-9568</issn><issn>1520-5134</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2012</creationdate><recordtype>article</recordtype><recordid>eNptkU1rGzEQhkVIIE7aQ_7BXAr1YVNJ--lDD47zUVOXBuqkx2WqHWEZ7WqRZEL_YH9X5LgEAjnNwPvOMy8zjF0Ifim4FF-2lHMu6vLpiE1EKXlWirw4ZhOexGxWVs0pOwthyzkvaikm7N89-mjQwg9n0cMy0BC9G42ChetHTyEYNwTAoYO3zkdndz0FcBp-kSUVqYMrj4PapGZuzbjBmChzq9zG2USIsBy0GUwkuDZ2FxMXzAC_MZLfq2vqR_IYd2kpaO96WMNX-CzrBqKDXDRT-P6SYx57F8YN-YS_3ydMEx_YiUYb6OP_es4ebm_Wi2_Z6ufdcjFfZShnVcyKupCaa-JVVxd_GqkKyrFWSmKDWqWLVEp0CjnvhJ5VM8QOVaU63lFTNLks83M2PXCVdyF40u3oTY_-byt4u39A-_qA5P108KIK7dbt_JCSveN7BjLmh2M</recordid><startdate>20120510</startdate><enddate>20120510</enddate><creator>Šimurka, Lukáš</creator><creator>Cibulka, Ivan</creator><creator>Hnědkovský, Lubomír</creator><general>American Chemical Society</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20120510</creationdate><title>Partial Molar Isentropic Compressions and Partial Molar Volumes of Selected Branched Aliphatic Alcohols at Infinite Dilution in Water at Temperatures from T = (278 to 318) K and Atmospheric Pressure</title><author>Šimurka, Lukáš ; Cibulka, Ivan ; Hnědkovský, Lubomír</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a296t-4742f0fe06d74b82c4e3a7cc2a8afc4726c1dca00d1f969aadac6cd0de8483253</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2012</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Šimurka, Lukáš</creatorcontrib><creatorcontrib>Cibulka, Ivan</creatorcontrib><creatorcontrib>Hnědkovský, Lubomír</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of chemical and engineering data</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Šimurka, Lukáš</au><au>Cibulka, Ivan</au><au>Hnědkovský, Lubomír</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Partial Molar Isentropic Compressions and Partial Molar Volumes of Selected Branched Aliphatic Alcohols at Infinite Dilution in Water at Temperatures from T = (278 to 318) K and Atmospheric Pressure</atitle><jtitle>Journal of chemical and engineering data</jtitle><addtitle>J. Chem. Eng. Data</addtitle><date>2012-05-10</date><risdate>2012</risdate><volume>57</volume><issue>5</issue><spage>1570</spage><epage>1580</epage><pages>1570-1580</pages><issn>0021-9568</issn><eissn>1520-5134</eissn><abstract>Speed of sound data for dilute aqueous solutions of one monohydric alcohol (2,2-dimethylpropane-1-ol), five polyhydric alcohols (2-methylpropane-1,3-diol, 2,2-dimethylpropane-1,3-diol, 2,2-bis(hydroxymethyl)propane-1-ol, 2,2-bis(hydroxymethyl)propane-1,3-diol, 2,2-bis(hydroxymethyl)butane-1-ol), and one ether alcohol (3,3,7,7-tetrakis(hydroxymethyl)-5-oxanonane) were obtained using the Anton Paar DSA 5000 vibrating-tube densimeter and sound analyzer in the temperature range from (278.15 to 318.15) K and at atmospheric pressure. Standard molar isentropic compressions were evaluated from the measured data. Measured densities of dilute aqueous solutions of 2,2-dimethylpropane-1,3-diol and 2,2-bis(hydroxymethyl)propane-1,3-diol are also presented along with the standard molar volumes of these two solutes calculated from the measured data. Relations between the two standard quantities and molecular structures of the solutes are discussed.</abstract><pub>American Chemical Society</pub><doi>10.1021/je300175w</doi><tpages>11</tpages></addata></record> |
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title | Partial Molar Isentropic Compressions and Partial Molar Volumes of Selected Branched Aliphatic Alcohols at Infinite Dilution in Water at Temperatures from T = (278 to 318) K and Atmospheric Pressure |
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