Electrical Conductivities, Viscosities, and Densities of N-Methoxymethyl- and N-Butyl-N-methylpyrrolidinium Ionic Liquids with the Bis(fluorosulfonyl)amide Anion

Electrical Conductivities, Viscosities, and Densities of N-Methoxymethyl- and N-Butyl-N-methylpyrrolidinium Ionic Liquids with the Bis(fluorosulfonyl)amide Anion

This paper reports the densities, viscosities, and electrical conductivities of the two pyrrolidinium ionic liquids, N-methoxymethyl-N-methylpyrrolidinium bis­(fluorosulfonyl)­amide ([Pyr1,1O1]­[FSA]) and N-butyl-N-methylpyrrolidinium bis­(fluorosulfonyl)­amide ([Pyr1,4]­[FSA]), over the temperature...

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Veröffentlicht in:Journal of chemical and engineering data 2012-03, Vol.57 (3), p.751-755
Hauptverfasser: Makino, Takashi, Kanakubo, Mitsuhiro, Umecky, Tatsuya, Suzuki, Akira, Nishida, Tetsuo, Takano, Jun
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container_title Journal of chemical and engineering data
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creator Makino, Takashi
Kanakubo, Mitsuhiro
Umecky, Tatsuya
Suzuki, Akira
Nishida, Tetsuo
Takano, Jun
description This paper reports the densities, viscosities, and electrical conductivities of the two pyrrolidinium ionic liquids, N-methoxymethyl-N-methylpyrrolidinium bis­(fluorosulfonyl)­amide ([Pyr1,1O1]­[FSA]) and N-butyl-N-methylpyrrolidinium bis­(fluorosulfonyl)­amide ([Pyr1,4]­[FSA]), over the temperature range T = (273.15 to 363.15) K at atmospheric pressure. The densities were fitted to polynominals, and the viscosities and electrical conductivities were analyzed with the Vogel–Fulcher–Tammann and Litovitz equations. The densities and electrical conductivities of [Pyr1,1O1]­[FSA] are higher than those of [Pyr1,4]­[FSA], while the viscosities of the former salt are smaller than those of the latter. The Walden plots (double logarithm graph of molar conductivity vs fluidity (reciprocal viscosity)) give the straight lines with the slopes being 0.91 to 0.94. The present results for [Pyr1,1O1]­[FSA] and [Pyr1,4]­[FSA] are compared with those for the bis­(trifluoromethanesulfonyl)­amide ([NTf2]−) analogues, [Pyr1,1O1]­[NTf2] and [Pyr1,4]­[NTf2].
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The densities were fitted to polynominals, and the viscosities and electrical conductivities were analyzed with the Vogel–Fulcher–Tammann and Litovitz equations. The densities and electrical conductivities of [Pyr1,1O1]­[FSA] are higher than those of [Pyr1,4]­[FSA], while the viscosities of the former salt are smaller than those of the latter. The Walden plots (double logarithm graph of molar conductivity vs fluidity (reciprocal viscosity)) give the straight lines with the slopes being 0.91 to 0.94. The present results for [Pyr1,1O1]­[FSA] and [Pyr1,4]­[FSA] are compared with those for the bis­(trifluoromethanesulfonyl)­amide ([NTf2]−) analogues, [Pyr1,1O1]­[NTf2] and [Pyr1,4]­[NTf2].</description><identifier>ISSN: 0021-9568</identifier><identifier>EISSN: 1520-5134</identifier><identifier>DOI: 10.1021/je200864h</identifier><language>eng</language><publisher>American Chemical Society</publisher><ispartof>Journal of chemical and engineering data, 2012-03, Vol.57 (3), p.751-755</ispartof><rights>Copyright © 2012 American Chemical Society</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a259t-b2f07ac41228c018dc0a513b36837c780e9f66d252227eae6963a2af45affd773</citedby><cites>FETCH-LOGICAL-a259t-b2f07ac41228c018dc0a513b36837c780e9f66d252227eae6963a2af45affd773</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/je200864h$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/je200864h$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,780,784,2765,27076,27924,27925,56738,56788</link.rule.ids></links><search><creatorcontrib>Makino, Takashi</creatorcontrib><creatorcontrib>Kanakubo, Mitsuhiro</creatorcontrib><creatorcontrib>Umecky, Tatsuya</creatorcontrib><creatorcontrib>Suzuki, Akira</creatorcontrib><creatorcontrib>Nishida, Tetsuo</creatorcontrib><creatorcontrib>Takano, Jun</creatorcontrib><title>Electrical Conductivities, Viscosities, and Densities of N-Methoxymethyl- and N-Butyl-N-methylpyrrolidinium Ionic Liquids with the Bis(fluorosulfonyl)amide Anion</title><title>Journal of chemical and engineering data</title><addtitle>J. Chem. Eng. Data</addtitle><description>This paper reports the densities, viscosities, and electrical conductivities of the two pyrrolidinium ionic liquids, N-methoxymethyl-N-methylpyrrolidinium bis­(fluorosulfonyl)­amide ([Pyr1,1O1]­[FSA]) and N-butyl-N-methylpyrrolidinium bis­(fluorosulfonyl)­amide ([Pyr1,4]­[FSA]), over the temperature range T = (273.15 to 363.15) K at atmospheric pressure. The densities were fitted to polynominals, and the viscosities and electrical conductivities were analyzed with the Vogel–Fulcher–Tammann and Litovitz equations. The densities and electrical conductivities of [Pyr1,1O1]­[FSA] are higher than those of [Pyr1,4]­[FSA], while the viscosities of the former salt are smaller than those of the latter. The Walden plots (double logarithm graph of molar conductivity vs fluidity (reciprocal viscosity)) give the straight lines with the slopes being 0.91 to 0.94. The present results for [Pyr1,1O1]­[FSA] and [Pyr1,4]­[FSA] are compared with those for the bis­(trifluoromethanesulfonyl)­amide ([NTf2]−) analogues, [Pyr1,1O1]­[NTf2] and [Pyr1,4]­[NTf2].</description><issn>0021-9568</issn><issn>1520-5134</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2012</creationdate><recordtype>article</recordtype><recordid>eNptkM1OwzAQhC0EEqVw4A18QaISBtv5P7alQKVSLsA1cv2juHLsEjtAHoc3JZCKE6fR7H5azQ4A5wRfE0zJzVZSjPM0rg7AiCQUo4RE8SEY4X6JiiTNj8GJ91uMcZxRMgJfCyN5aDRnBs6dFS0P-l0HLf0VfNWeO783zAp4K-1goVNwjR5lqNxnV_fSGfRLrNGsDb1Zo2G665rGGS201W0Nl85qDlf6rdXCww8dKhgqCWfaXyrTusb51ihnOzNhtRYSTq129hQcKWa8PNvrGLzcLZ7nD2j1dL-cT1eI0aQIaEMVzhiPCaU5xyQXHLP-902U5lHGsxzLQqWpoAmlNJNMpkUaMcpUnDClRJZFYzAZ7vI-h2-kKneNrlnTlQSXP92Wf9327MXAMu7LrWsb2yf7h_sGNA57xw</recordid><startdate>20120308</startdate><enddate>20120308</enddate><creator>Makino, Takashi</creator><creator>Kanakubo, Mitsuhiro</creator><creator>Umecky, Tatsuya</creator><creator>Suzuki, Akira</creator><creator>Nishida, Tetsuo</creator><creator>Takano, Jun</creator><general>American Chemical Society</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20120308</creationdate><title>Electrical Conductivities, Viscosities, and Densities of N-Methoxymethyl- and N-Butyl-N-methylpyrrolidinium Ionic Liquids with the Bis(fluorosulfonyl)amide Anion</title><author>Makino, Takashi ; Kanakubo, Mitsuhiro ; Umecky, Tatsuya ; Suzuki, Akira ; Nishida, Tetsuo ; Takano, Jun</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a259t-b2f07ac41228c018dc0a513b36837c780e9f66d252227eae6963a2af45affd773</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2012</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Makino, Takashi</creatorcontrib><creatorcontrib>Kanakubo, Mitsuhiro</creatorcontrib><creatorcontrib>Umecky, Tatsuya</creatorcontrib><creatorcontrib>Suzuki, Akira</creatorcontrib><creatorcontrib>Nishida, Tetsuo</creatorcontrib><creatorcontrib>Takano, Jun</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of chemical and engineering data</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Makino, Takashi</au><au>Kanakubo, Mitsuhiro</au><au>Umecky, Tatsuya</au><au>Suzuki, Akira</au><au>Nishida, Tetsuo</au><au>Takano, Jun</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Electrical Conductivities, Viscosities, and Densities of N-Methoxymethyl- and N-Butyl-N-methylpyrrolidinium Ionic Liquids with the Bis(fluorosulfonyl)amide Anion</atitle><jtitle>Journal of chemical and engineering data</jtitle><addtitle>J. Chem. Eng. Data</addtitle><date>2012-03-08</date><risdate>2012</risdate><volume>57</volume><issue>3</issue><spage>751</spage><epage>755</epage><pages>751-755</pages><issn>0021-9568</issn><eissn>1520-5134</eissn><abstract>This paper reports the densities, viscosities, and electrical conductivities of the two pyrrolidinium ionic liquids, N-methoxymethyl-N-methylpyrrolidinium bis­(fluorosulfonyl)­amide ([Pyr1,1O1]­[FSA]) and N-butyl-N-methylpyrrolidinium bis­(fluorosulfonyl)­amide ([Pyr1,4]­[FSA]), over the temperature range T = (273.15 to 363.15) K at atmospheric pressure. The densities were fitted to polynominals, and the viscosities and electrical conductivities were analyzed with the Vogel–Fulcher–Tammann and Litovitz equations. The densities and electrical conductivities of [Pyr1,1O1]­[FSA] are higher than those of [Pyr1,4]­[FSA], while the viscosities of the former salt are smaller than those of the latter. The Walden plots (double logarithm graph of molar conductivity vs fluidity (reciprocal viscosity)) give the straight lines with the slopes being 0.91 to 0.94. The present results for [Pyr1,1O1]­[FSA] and [Pyr1,4]­[FSA] are compared with those for the bis­(trifluoromethanesulfonyl)­amide ([NTf2]−) analogues, [Pyr1,1O1]­[NTf2] and [Pyr1,4]­[NTf2].</abstract><pub>American Chemical Society</pub><doi>10.1021/je200864h</doi><tpages>5</tpages></addata></record>
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