Effects of Isomeric Alcohols and Oils on the Properties of the Microemulsion Systems Formed by Alkyl Phenol Poly(oxyethylene ether)

Effects of Isomeric Alcohols and Oils on the Properties of the Microemulsion Systems Formed by Alkyl Phenol Poly(oxyethylene ether)

The effects of three isomeric alcohols, butan-1-ol, butan-2-ol, and 2-methyl-propan-2-ol, on the phase behavior and physicochemical properties of the pseudoquaternary microemulsion systems alkyl phenol poly(oxyethylene ether) (OP) + butan-1-ol (butan-2-ol, 2-methyl-propan-2-ol) + hexane (heptane, oc...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Journal of chemical and engineering data 2010-11, Vol.55 (11), p.4912-4916
Hauptverfasser: Chai, Jin-ling, Xue, Xiao-nan, Zhang, Zai-mei, Li, Xun-qiang, Shang, Shu-chuan, Lu, Jian-jun
Format: Artikel
Sprache:eng
Schlagworte:
Chemistry
Colloidal state and disperse state
Emulsions. Microemulsions. Foams
Exact sciences and technology
General and physical chemistry
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 4916
container_issue 11
container_start_page 4912
container_title Journal of chemical and engineering data
container_volume 55
creator Chai, Jin-ling
Xue, Xiao-nan
Zhang, Zai-mei
Li, Xun-qiang
Shang, Shu-chuan
Lu, Jian-jun
description The effects of three isomeric alcohols, butan-1-ol, butan-2-ol, and 2-methyl-propan-2-ol, on the phase behavior and physicochemical properties of the pseudoquaternary microemulsion systems alkyl phenol poly(oxyethylene ether) (OP) + butan-1-ol (butan-2-ol, 2-methyl-propan-2-ol) + hexane (heptane, octane) + 0.05 NaCl solution were investigated with an ε−β fishlike phase diagram method. The properties studied include the composition of the interfacial layer A S, the solubilities of alcohols A O,W, and the solubilization ability SP* of the microemulsion systems. With the branched chain increasing, the A S and A O,W values are in the order: butan-1-ol < butan-2-ol < 2-methyl-propan-2-ol, but the SP* values are in the inverse order. These results were discussed. The effects of oils on the phase behavior and above physicochemical properties were also investigated.
doi_str_mv 10.1021/je100447e
format Article
fullrecord <record><control><sourceid>acs_cross</sourceid><recordid>TN_cdi_crossref_primary_10_1021_je100447e</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>b39485044</sourcerecordid><originalsourceid>FETCH-LOGICAL-a289t-f248f71d78e087393c62efa829c1fe0a94afaf66fd804b3e34cb3232532bf03f3</originalsourceid><addsrcrecordid>eNptkE1LAzEQhoMoWKsH_0Eugj2s5mM_ssdSWi1UWlDPSzY7YbdmNyXZgnv2j5taqRdP8zLzzMvMi9AtJQ-UMPq4BUpIHGdwhkY0YSRKKI_P0YiEYZQnqbhEV95vSYAyRkfoa641qN5jq_HS2xZco_DUKFtb47HsKrxugrAd7mvAG2d34PoGfvhD56VRzkK7N74JzOvge2g9XljXQoXLIVh9DAZvauhsKNYM9_ZzgL4eDHSAgwA3uUYXWhoPN791jN4X87fZc7RaPy1n01Ukmcj7SLNY6IxWmQAiMp5zlTLQUrBcUQ1E5rHUUqeprgSJSw48ViVnnCWclZpwzcdocvQNJ3vvQBc717TSDQUlxSG94pReYO-O7E56JY12slONPy0wHnNBEvHHSeWLrd27Lnzwj983Ql980Q</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Effects of Isomeric Alcohols and Oils on the Properties of the Microemulsion Systems Formed by Alkyl Phenol Poly(oxyethylene ether)</title><source>American Chemical Society Journals</source><creator>Chai, Jin-ling ; Xue, Xiao-nan ; Zhang, Zai-mei ; Li, Xun-qiang ; Shang, Shu-chuan ; Lu, Jian-jun</creator><creatorcontrib>Chai, Jin-ling ; Xue, Xiao-nan ; Zhang, Zai-mei ; Li, Xun-qiang ; Shang, Shu-chuan ; Lu, Jian-jun</creatorcontrib><description>The effects of three isomeric alcohols, butan-1-ol, butan-2-ol, and 2-methyl-propan-2-ol, on the phase behavior and physicochemical properties of the pseudoquaternary microemulsion systems alkyl phenol poly(oxyethylene ether) (OP) + butan-1-ol (butan-2-ol, 2-methyl-propan-2-ol) + hexane (heptane, octane) + 0.05 NaCl solution were investigated with an ε−β fishlike phase diagram method. The properties studied include the composition of the interfacial layer A S, the solubilities of alcohols A O,W, and the solubilization ability SP* of the microemulsion systems. With the branched chain increasing, the A S and A O,W values are in the order: butan-1-ol &lt; butan-2-ol &lt; 2-methyl-propan-2-ol, but the SP* values are in the inverse order. These results were discussed. The effects of oils on the phase behavior and above physicochemical properties were also investigated.</description><identifier>ISSN: 0021-9568</identifier><identifier>EISSN: 1520-5134</identifier><identifier>DOI: 10.1021/je100447e</identifier><identifier>CODEN: JCEAAX</identifier><language>eng</language><publisher>Washington, DC: American Chemical Society</publisher><subject>Chemistry ; Colloidal state and disperse state ; Emulsions. Microemulsions. Foams ; Exact sciences and technology ; General and physical chemistry</subject><ispartof>Journal of chemical and engineering data, 2010-11, Vol.55 (11), p.4912-4916</ispartof><rights>Copyright © 2010 American Chemical Society</rights><rights>2015 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a289t-f248f71d78e087393c62efa829c1fe0a94afaf66fd804b3e34cb3232532bf03f3</citedby><cites>FETCH-LOGICAL-a289t-f248f71d78e087393c62efa829c1fe0a94afaf66fd804b3e34cb3232532bf03f3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/je100447e$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/je100447e$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,776,780,2752,27053,27901,27902,56713,56763</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&amp;idt=23438058$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Chai, Jin-ling</creatorcontrib><creatorcontrib>Xue, Xiao-nan</creatorcontrib><creatorcontrib>Zhang, Zai-mei</creatorcontrib><creatorcontrib>Li, Xun-qiang</creatorcontrib><creatorcontrib>Shang, Shu-chuan</creatorcontrib><creatorcontrib>Lu, Jian-jun</creatorcontrib><title>Effects of Isomeric Alcohols and Oils on the Properties of the Microemulsion Systems Formed by Alkyl Phenol Poly(oxyethylene ether)</title><title>Journal of chemical and engineering data</title><addtitle>J. Chem. Eng. Data</addtitle><description>The effects of three isomeric alcohols, butan-1-ol, butan-2-ol, and 2-methyl-propan-2-ol, on the phase behavior and physicochemical properties of the pseudoquaternary microemulsion systems alkyl phenol poly(oxyethylene ether) (OP) + butan-1-ol (butan-2-ol, 2-methyl-propan-2-ol) + hexane (heptane, octane) + 0.05 NaCl solution were investigated with an ε−β fishlike phase diagram method. The properties studied include the composition of the interfacial layer A S, the solubilities of alcohols A O,W, and the solubilization ability SP* of the microemulsion systems. With the branched chain increasing, the A S and A O,W values are in the order: butan-1-ol &lt; butan-2-ol &lt; 2-methyl-propan-2-ol, but the SP* values are in the inverse order. These results were discussed. The effects of oils on the phase behavior and above physicochemical properties were also investigated.</description><subject>Chemistry</subject><subject>Colloidal state and disperse state</subject><subject>Emulsions. Microemulsions. Foams</subject><subject>Exact sciences and technology</subject><subject>General and physical chemistry</subject><issn>0021-9568</issn><issn>1520-5134</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2010</creationdate><recordtype>article</recordtype><recordid>eNptkE1LAzEQhoMoWKsH_0Eugj2s5mM_ssdSWi1UWlDPSzY7YbdmNyXZgnv2j5taqRdP8zLzzMvMi9AtJQ-UMPq4BUpIHGdwhkY0YSRKKI_P0YiEYZQnqbhEV95vSYAyRkfoa641qN5jq_HS2xZco_DUKFtb47HsKrxugrAd7mvAG2d34PoGfvhD56VRzkK7N74JzOvge2g9XljXQoXLIVh9DAZvauhsKNYM9_ZzgL4eDHSAgwA3uUYXWhoPN791jN4X87fZc7RaPy1n01Ukmcj7SLNY6IxWmQAiMp5zlTLQUrBcUQ1E5rHUUqeprgSJSw48ViVnnCWclZpwzcdocvQNJ3vvQBc717TSDQUlxSG94pReYO-O7E56JY12slONPy0wHnNBEvHHSeWLrd27Lnzwj983Ql980Q</recordid><startdate>20101111</startdate><enddate>20101111</enddate><creator>Chai, Jin-ling</creator><creator>Xue, Xiao-nan</creator><creator>Zhang, Zai-mei</creator><creator>Li, Xun-qiang</creator><creator>Shang, Shu-chuan</creator><creator>Lu, Jian-jun</creator><general>American Chemical Society</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20101111</creationdate><title>Effects of Isomeric Alcohols and Oils on the Properties of the Microemulsion Systems Formed by Alkyl Phenol Poly(oxyethylene ether)</title><author>Chai, Jin-ling ; Xue, Xiao-nan ; Zhang, Zai-mei ; Li, Xun-qiang ; Shang, Shu-chuan ; Lu, Jian-jun</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a289t-f248f71d78e087393c62efa829c1fe0a94afaf66fd804b3e34cb3232532bf03f3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2010</creationdate><topic>Chemistry</topic><topic>Colloidal state and disperse state</topic><topic>Emulsions. Microemulsions. Foams</topic><topic>Exact sciences and technology</topic><topic>General and physical chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Chai, Jin-ling</creatorcontrib><creatorcontrib>Xue, Xiao-nan</creatorcontrib><creatorcontrib>Zhang, Zai-mei</creatorcontrib><creatorcontrib>Li, Xun-qiang</creatorcontrib><creatorcontrib>Shang, Shu-chuan</creatorcontrib><creatorcontrib>Lu, Jian-jun</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><jtitle>Journal of chemical and engineering data</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Chai, Jin-ling</au><au>Xue, Xiao-nan</au><au>Zhang, Zai-mei</au><au>Li, Xun-qiang</au><au>Shang, Shu-chuan</au><au>Lu, Jian-jun</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Effects of Isomeric Alcohols and Oils on the Properties of the Microemulsion Systems Formed by Alkyl Phenol Poly(oxyethylene ether)</atitle><jtitle>Journal of chemical and engineering data</jtitle><addtitle>J. Chem. Eng. Data</addtitle><date>2010-11-11</date><risdate>2010</risdate><volume>55</volume><issue>11</issue><spage>4912</spage><epage>4916</epage><pages>4912-4916</pages><issn>0021-9568</issn><eissn>1520-5134</eissn><coden>JCEAAX</coden><abstract>The effects of three isomeric alcohols, butan-1-ol, butan-2-ol, and 2-methyl-propan-2-ol, on the phase behavior and physicochemical properties of the pseudoquaternary microemulsion systems alkyl phenol poly(oxyethylene ether) (OP) + butan-1-ol (butan-2-ol, 2-methyl-propan-2-ol) + hexane (heptane, octane) + 0.05 NaCl solution were investigated with an ε−β fishlike phase diagram method. The properties studied include the composition of the interfacial layer A S, the solubilities of alcohols A O,W, and the solubilization ability SP* of the microemulsion systems. With the branched chain increasing, the A S and A O,W values are in the order: butan-1-ol &lt; butan-2-ol &lt; 2-methyl-propan-2-ol, but the SP* values are in the inverse order. These results were discussed. The effects of oils on the phase behavior and above physicochemical properties were also investigated.</abstract><cop>Washington, DC</cop><pub>American Chemical Society</pub><doi>10.1021/je100447e</doi><tpages>5</tpages></addata></record>
fulltext fulltext
identifier ISSN: 0021-9568
ispartof Journal of chemical and engineering data, 2010-11, Vol.55 (11), p.4912-4916
issn 0021-9568
1520-5134
language eng
recordid cdi_crossref_primary_10_1021_je100447e
source American Chemical Society Journals
subjects Chemistry
Colloidal state and disperse state
Emulsions. Microemulsions. Foams
Exact sciences and technology
General and physical chemistry
title Effects of Isomeric Alcohols and Oils on the Properties of the Microemulsion Systems Formed by Alkyl Phenol Poly(oxyethylene ether)
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-01T09%3A42%3A06IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-acs_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Effects%20of%20Isomeric%20Alcohols%20and%20Oils%20on%20the%20Properties%20of%20the%20Microemulsion%20Systems%20Formed%20by%20Alkyl%20Phenol%20Poly(oxyethylene%20ether)&rft.jtitle=Journal%20of%20chemical%20and%20engineering%20data&rft.au=Chai,%20Jin-ling&rft.date=2010-11-11&rft.volume=55&rft.issue=11&rft.spage=4912&rft.epage=4916&rft.pages=4912-4916&rft.issn=0021-9568&rft.eissn=1520-5134&rft.coden=JCEAAX&rft_id=info:doi/10.1021/je100447e&rft_dat=%3Cacs_cross%3Eb39485044%3C/acs_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true