Phase Behavior of Alcohol-Free Microemulsion Systems Containing Butyric Acid as a Cosurfactant
The phase behavior of the alcohol-free microemulsion systems comprising of sodium dodecyl sulfate (SDS) + butyric acid + alkane + NaCl solution has been studied with an ε−β fishlike phase diagram method. The composition of the hydrophile−lipophile balanced (HLB) interfacial layer, the solubility of...
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Veröffentlicht in: | Journal of chemical and engineering data 2010-09, Vol.55 (9), p.3224-3228 |
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creator | Li, Xun-qiang Chai, Jin-ling Shang, Shu-chuan Li, Hong-liang Lu, Jian-jun Yang, Bao Wu, Yu-tong |
description | The phase behavior of the alcohol-free microemulsion systems comprising of sodium dodecyl sulfate (SDS) + butyric acid + alkane + NaCl solution has been studied with an ε−β fishlike phase diagram method. The composition of the hydrophile−lipophile balanced (HLB) interfacial layer, the solubility of butyric acid, and the solubilization ability of the system, and so forth, were determined. The effects of the composition of the water phase, such as salts, acids, and alkali, and temperature on the phase behavior were investigated. As the salinity increases, the solubilization ability increases. The cations of the salts have notable influence on the phase diagrams. The influence of acid (HCl) is similar to that of salt (NaCl). However, alkali (NaOH) can remarkably affect the phase diagrams and shift the fish body to an upper position. A comparison of the ε−β phase diagrams is also made between the butyric acid-containing microemulsion systems and the 1-butanol-containing microemulsion systems. |
doi_str_mv | 10.1021/je100060t |
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The composition of the hydrophile−lipophile balanced (HLB) interfacial layer, the solubility of butyric acid, and the solubilization ability of the system, and so forth, were determined. The effects of the composition of the water phase, such as salts, acids, and alkali, and temperature on the phase behavior were investigated. As the salinity increases, the solubilization ability increases. The cations of the salts have notable influence on the phase diagrams. The influence of acid (HCl) is similar to that of salt (NaCl). However, alkali (NaOH) can remarkably affect the phase diagrams and shift the fish body to an upper position. A comparison of the ε−β phase diagrams is also made between the butyric acid-containing microemulsion systems and the 1-butanol-containing microemulsion systems.</description><identifier>ISSN: 0021-9568</identifier><identifier>EISSN: 1520-5134</identifier><identifier>DOI: 10.1021/je100060t</identifier><identifier>CODEN: JCEAAX</identifier><language>eng</language><publisher>Washington, DC: American Chemical Society</publisher><subject>Chemistry ; Colloidal state and disperse state ; Emulsions. Microemulsions. Foams ; Exact sciences and technology ; General and physical chemistry ; Phase equilibria</subject><ispartof>Journal of chemical and engineering data, 2010-09, Vol.55 (9), p.3224-3228</ispartof><rights>Copyright © 2010 American Chemical Society</rights><rights>2015 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a289t-9e0b670a8c2a125cdfa3f261ec99e4535e59fae546e4ddea2f9413a88349c04a3</citedby><cites>FETCH-LOGICAL-a289t-9e0b670a8c2a125cdfa3f261ec99e4535e59fae546e4ddea2f9413a88349c04a3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/je100060t$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/je100060t$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,776,780,2751,27055,27903,27904,56717,56767</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=23212196$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Li, Xun-qiang</creatorcontrib><creatorcontrib>Chai, Jin-ling</creatorcontrib><creatorcontrib>Shang, Shu-chuan</creatorcontrib><creatorcontrib>Li, Hong-liang</creatorcontrib><creatorcontrib>Lu, Jian-jun</creatorcontrib><creatorcontrib>Yang, Bao</creatorcontrib><creatorcontrib>Wu, Yu-tong</creatorcontrib><title>Phase Behavior of Alcohol-Free Microemulsion Systems Containing Butyric Acid as a Cosurfactant</title><title>Journal of chemical and engineering data</title><addtitle>J. Chem. Eng. Data</addtitle><description>The phase behavior of the alcohol-free microemulsion systems comprising of sodium dodecyl sulfate (SDS) + butyric acid + alkane + NaCl solution has been studied with an ε−β fishlike phase diagram method. The composition of the hydrophile−lipophile balanced (HLB) interfacial layer, the solubility of butyric acid, and the solubilization ability of the system, and so forth, were determined. The effects of the composition of the water phase, such as salts, acids, and alkali, and temperature on the phase behavior were investigated. As the salinity increases, the solubilization ability increases. The cations of the salts have notable influence on the phase diagrams. The influence of acid (HCl) is similar to that of salt (NaCl). However, alkali (NaOH) can remarkably affect the phase diagrams and shift the fish body to an upper position. A comparison of the ε−β phase diagrams is also made between the butyric acid-containing microemulsion systems and the 1-butanol-containing microemulsion systems.</description><subject>Chemistry</subject><subject>Colloidal state and disperse state</subject><subject>Emulsions. Microemulsions. Foams</subject><subject>Exact sciences and technology</subject><subject>General and physical chemistry</subject><subject>Phase equilibria</subject><issn>0021-9568</issn><issn>1520-5134</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2010</creationdate><recordtype>article</recordtype><recordid>eNptkDFPwzAUhC0EEqUw8A-8MDAEbMdO47GtKCCBQAJWoofzTF2ldmU7SP33BBWVhemG-97p3RFyztkVZ4Jfr5AzxiqWD8iIK8EKxUt5SEZsMAutqvqYnKS0Ghg5EXxE3p-XkJDOcAlfLkQaLJ12JixDVywiIn10JgZc911ywdOXbcq4TnQefAbnnf-ksz5vozN0alxLIVEYzNRHCyaDz6fkyEKX8OxXx-RtcfM6vysenm7v59OHAkStc6GRfVQTBrURwIUyrYXSioqj0RqlKhUqbQGVrFC2LYKwWvIS6rqU2jAJ5Zhc7nKHb1OKaJtNdGuI24az5meYZj_MwF7s2A0kA52N4I1L-wNRCi64rv44MKlZhT76ocE_ed-qNW9Y</recordid><startdate>20100909</startdate><enddate>20100909</enddate><creator>Li, Xun-qiang</creator><creator>Chai, Jin-ling</creator><creator>Shang, Shu-chuan</creator><creator>Li, Hong-liang</creator><creator>Lu, Jian-jun</creator><creator>Yang, Bao</creator><creator>Wu, Yu-tong</creator><general>American Chemical Society</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20100909</creationdate><title>Phase Behavior of Alcohol-Free Microemulsion Systems Containing Butyric Acid as a Cosurfactant</title><author>Li, Xun-qiang ; Chai, Jin-ling ; Shang, Shu-chuan ; Li, Hong-liang ; Lu, Jian-jun ; Yang, Bao ; Wu, Yu-tong</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a289t-9e0b670a8c2a125cdfa3f261ec99e4535e59fae546e4ddea2f9413a88349c04a3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2010</creationdate><topic>Chemistry</topic><topic>Colloidal state and disperse state</topic><topic>Emulsions. Microemulsions. Foams</topic><topic>Exact sciences and technology</topic><topic>General and physical chemistry</topic><topic>Phase equilibria</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Li, Xun-qiang</creatorcontrib><creatorcontrib>Chai, Jin-ling</creatorcontrib><creatorcontrib>Shang, Shu-chuan</creatorcontrib><creatorcontrib>Li, Hong-liang</creatorcontrib><creatorcontrib>Lu, Jian-jun</creatorcontrib><creatorcontrib>Yang, Bao</creatorcontrib><creatorcontrib>Wu, Yu-tong</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><jtitle>Journal of chemical and engineering data</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Li, Xun-qiang</au><au>Chai, Jin-ling</au><au>Shang, Shu-chuan</au><au>Li, Hong-liang</au><au>Lu, Jian-jun</au><au>Yang, Bao</au><au>Wu, Yu-tong</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Phase Behavior of Alcohol-Free Microemulsion Systems Containing Butyric Acid as a Cosurfactant</atitle><jtitle>Journal of chemical and engineering data</jtitle><addtitle>J. Chem. Eng. Data</addtitle><date>2010-09-09</date><risdate>2010</risdate><volume>55</volume><issue>9</issue><spage>3224</spage><epage>3228</epage><pages>3224-3228</pages><issn>0021-9568</issn><eissn>1520-5134</eissn><coden>JCEAAX</coden><abstract>The phase behavior of the alcohol-free microemulsion systems comprising of sodium dodecyl sulfate (SDS) + butyric acid + alkane + NaCl solution has been studied with an ε−β fishlike phase diagram method. The composition of the hydrophile−lipophile balanced (HLB) interfacial layer, the solubility of butyric acid, and the solubilization ability of the system, and so forth, were determined. The effects of the composition of the water phase, such as salts, acids, and alkali, and temperature on the phase behavior were investigated. As the salinity increases, the solubilization ability increases. The cations of the salts have notable influence on the phase diagrams. The influence of acid (HCl) is similar to that of salt (NaCl). However, alkali (NaOH) can remarkably affect the phase diagrams and shift the fish body to an upper position. A comparison of the ε−β phase diagrams is also made between the butyric acid-containing microemulsion systems and the 1-butanol-containing microemulsion systems.</abstract><cop>Washington, DC</cop><pub>American Chemical Society</pub><doi>10.1021/je100060t</doi><tpages>5</tpages></addata></record> |
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subjects | Chemistry Colloidal state and disperse state Emulsions. Microemulsions. Foams Exact sciences and technology General and physical chemistry Phase equilibria |
title | Phase Behavior of Alcohol-Free Microemulsion Systems Containing Butyric Acid as a Cosurfactant |
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