PVT Property Measurements for Some Aliphatic Esters from (298 to 393) K and up to 35 MPa

PVT Property Measurements for Some Aliphatic Esters from (298 to 393) K and up to 35 MPa

The results of PVT measurements of the liquid phase within the temperature range of (298 to 393) K and up to 35 MPa are presented for some aliphatic esters. Measurements were made by means of a vibrating-tube densimeter, model DMA 512P from Anton Parr. The calibration of the densimeter was performed...

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Veröffentlicht in:Journal of chemical and engineering data 2007-05, Vol.52 (3), p.737-751
Hauptverfasser: Gardas, Ramesh L, Johnson, Irudayaraj, Vaz, David M. D, Fonseca, Isabel M. A, Ferreira, Abel G. M
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Chemical thermodynamics
Chemistry
Exact sciences and technology
General and physical chemistry
General. Theory
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container_issue 3
container_start_page 737
container_title Journal of chemical and engineering data
container_volume 52
creator Gardas, Ramesh L
Johnson, Irudayaraj
Vaz, David M. D
Fonseca, Isabel M. A
Ferreira, Abel G. M
description The results of PVT measurements of the liquid phase within the temperature range of (298 to 393) K and up to 35 MPa are presented for some aliphatic esters. Measurements were made by means of a vibrating-tube densimeter, model DMA 512P from Anton Parr. The calibration of the densimeter was performed with water and n-heptane as reference fluids. The experimental PVT data have been correlated by a Tait equation. This equation gives excellent results when used to predict the density of the esters using the method proposed by Thomson et al. (AIChE J. 1982, 28, 671−676). Isothermal compressibilities, isobaric expansivities, thermal pressure coefficients, and changes in the isobaric heat capacity have been calculated from the volumetric data.
doi_str_mv 10.1021/je060339m
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subjects Chemical thermodynamics
Chemistry
Exact sciences and technology
General and physical chemistry
General. Theory
title PVT Property Measurements for Some Aliphatic Esters from (298 to 393) K and up to 35 MPa
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