Volumetric and Speed of Sound of Ionic Liquid, 1-Butyl-3-methylimidazolium Hexafluorophosphate with Acetonitrile and Methanol at T = (298.15 to 318.15) K

Volumetric and Speed of Sound of Ionic Liquid, 1-Butyl-3-methylimidazolium Hexafluorophosphate with Acetonitrile and Methanol at T = (298.15 to 318.15) K

We report the density (ρ) and speed of sound (u) data for 1-butyl-3-methylimidazolium hexafluorophosphate ([BMIM][PF6]) + methanol and ([BMIM][PF6]) + acetonitrile binary mixtures over the entire range of their compositions at T = (298.15 to 318.15) K. From these data, excess molar volume and isentr...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Journal of chemical and engineering data 2005-09, Vol.50 (5), p.1694-1699
Hauptverfasser: Zafarani-Moattar, Mohammed Taghi, Shekaari, Hemayat
Format: Artikel
Sprache:eng
Schlagworte:
Chemical thermodynamics
Chemistry
Exact sciences and technology
General and physical chemistry
Mixtures
Thermodynamic properties
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 1699
container_issue 5
container_start_page 1694
container_title Journal of chemical and engineering data
container_volume 50
creator Zafarani-Moattar, Mohammed Taghi
Shekaari, Hemayat
description We report the density (ρ) and speed of sound (u) data for 1-butyl-3-methylimidazolium hexafluorophosphate ([BMIM][PF6]) + methanol and ([BMIM][PF6]) + acetonitrile binary mixtures over the entire range of their compositions at T = (298.15 to 318.15) K. From these data, excess molar volume and isentropic compressibility deviation values have been calculated and fitted to the fourth-order Redlich−Kister equation. The excess molar volume values (V E) for acetonitrile mixtures are more negative than methanol mixtures. Isentropic compressibility deviation values (Δκs) in methanol mixtures are more than acetonitrile mixtures. The results have been interpreted in terms of ion−dipole interactions and structural factors of the ionic liquid and these organic solvents.
doi_str_mv 10.1021/je050165t
format Article
fullrecord <record><control><sourceid>istex_cross</sourceid><recordid>TN_cdi_crossref_primary_10_1021_je050165t</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>ark_67375_TPS_S9T8ZTKS_4</sourcerecordid><originalsourceid>FETCH-LOGICAL-a327t-72e21d79b6a59f661e33ffaf432df3485a846c1e4dc641b7bc21f84d91021cd73</originalsourceid><addsrcrecordid>eNptkM1u1DAUhS0EEkNhwRt4g0Ql3PraSZwsWJQK2qqDQEpgwSby-EfjwROntiM6vEnftpkOajes7pXOd87RvQi9BXoClMHpxtCSQlXmZ2gBJaOkBF48Rws6i6Qpq_olepXShlJaCAYLdPcz-GlrcnQKy0HjdjRG42BxG6bhYbkKw6wt3c3k9AcM5NOUd55wMpvWO--2Tsu_wbtpiy_NrbR-CjGM65DGtcwG_3F5jc-UyXPKXOLNQ8vX2SuH4LHMuMMf8XvW1CdQ4hwwh_12jK9foxdW-mTe_JtH6MeXz935JVl-u7g6P1sSyZnIRDDDQItmVcmysVUFhnNrpS0405YXdSnrolJgCq2qAlZipRjYutDN_l1KC36Ejg-5KoaUorH9GN1Wxl0PtN9D_eNPZ_bdgR1lUtLbKAfl0pNBAHDK65kjB86lbG4fdRl_95Xgouy7723fNl39q7tu--IpV6rUb8IUh_ni__TfA0LIkF8</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Volumetric and Speed of Sound of Ionic Liquid, 1-Butyl-3-methylimidazolium Hexafluorophosphate with Acetonitrile and Methanol at T = (298.15 to 318.15) K</title><source>ACS Publications</source><creator>Zafarani-Moattar, Mohammed Taghi ; Shekaari, Hemayat</creator><creatorcontrib>Zafarani-Moattar, Mohammed Taghi ; Shekaari, Hemayat</creatorcontrib><description>We report the density (ρ) and speed of sound (u) data for 1-butyl-3-methylimidazolium hexafluorophosphate ([BMIM][PF6]) + methanol and ([BMIM][PF6]) + acetonitrile binary mixtures over the entire range of their compositions at T = (298.15 to 318.15) K. From these data, excess molar volume and isentropic compressibility deviation values have been calculated and fitted to the fourth-order Redlich−Kister equation. The excess molar volume values (V E) for acetonitrile mixtures are more negative than methanol mixtures. Isentropic compressibility deviation values (Δκs) in methanol mixtures are more than acetonitrile mixtures. The results have been interpreted in terms of ion−dipole interactions and structural factors of the ionic liquid and these organic solvents.</description><identifier>ISSN: 0021-9568</identifier><identifier>EISSN: 1520-5134</identifier><identifier>DOI: 10.1021/je050165t</identifier><identifier>CODEN: JCEAAX</identifier><language>eng</language><publisher>Washington, DC: American Chemical Society</publisher><subject>Chemical thermodynamics ; Chemistry ; Exact sciences and technology ; General and physical chemistry ; Mixtures ; Thermodynamic properties</subject><ispartof>Journal of chemical and engineering data, 2005-09, Vol.50 (5), p.1694-1699</ispartof><rights>Copyright © 2005 American Chemical Society</rights><rights>2006 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a327t-72e21d79b6a59f661e33ffaf432df3485a846c1e4dc641b7bc21f84d91021cd73</citedby><cites>FETCH-LOGICAL-a327t-72e21d79b6a59f661e33ffaf432df3485a846c1e4dc641b7bc21f84d91021cd73</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/je050165t$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/je050165t$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,780,784,2763,27075,27923,27924,56737,56787</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&amp;idt=17113038$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Zafarani-Moattar, Mohammed Taghi</creatorcontrib><creatorcontrib>Shekaari, Hemayat</creatorcontrib><title>Volumetric and Speed of Sound of Ionic Liquid, 1-Butyl-3-methylimidazolium Hexafluorophosphate with Acetonitrile and Methanol at T = (298.15 to 318.15) K</title><title>Journal of chemical and engineering data</title><addtitle>J. Chem. Eng. Data</addtitle><description>We report the density (ρ) and speed of sound (u) data for 1-butyl-3-methylimidazolium hexafluorophosphate ([BMIM][PF6]) + methanol and ([BMIM][PF6]) + acetonitrile binary mixtures over the entire range of their compositions at T = (298.15 to 318.15) K. From these data, excess molar volume and isentropic compressibility deviation values have been calculated and fitted to the fourth-order Redlich−Kister equation. The excess molar volume values (V E) for acetonitrile mixtures are more negative than methanol mixtures. Isentropic compressibility deviation values (Δκs) in methanol mixtures are more than acetonitrile mixtures. The results have been interpreted in terms of ion−dipole interactions and structural factors of the ionic liquid and these organic solvents.</description><subject>Chemical thermodynamics</subject><subject>Chemistry</subject><subject>Exact sciences and technology</subject><subject>General and physical chemistry</subject><subject>Mixtures</subject><subject>Thermodynamic properties</subject><issn>0021-9568</issn><issn>1520-5134</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2005</creationdate><recordtype>article</recordtype><recordid>eNptkM1u1DAUhS0EEkNhwRt4g0Ql3PraSZwsWJQK2qqDQEpgwSby-EfjwROntiM6vEnftpkOajes7pXOd87RvQi9BXoClMHpxtCSQlXmZ2gBJaOkBF48Rws6i6Qpq_olepXShlJaCAYLdPcz-GlrcnQKy0HjdjRG42BxG6bhYbkKw6wt3c3k9AcM5NOUd55wMpvWO--2Tsu_wbtpiy_NrbR-CjGM65DGtcwG_3F5jc-UyXPKXOLNQ8vX2SuH4LHMuMMf8XvW1CdQ4hwwh_12jK9foxdW-mTe_JtH6MeXz935JVl-u7g6P1sSyZnIRDDDQItmVcmysVUFhnNrpS0405YXdSnrolJgCq2qAlZipRjYutDN_l1KC36Ejg-5KoaUorH9GN1Wxl0PtN9D_eNPZ_bdgR1lUtLbKAfl0pNBAHDK65kjB86lbG4fdRl_95Xgouy7723fNl39q7tu--IpV6rUb8IUh_ni__TfA0LIkF8</recordid><startdate>20050901</startdate><enddate>20050901</enddate><creator>Zafarani-Moattar, Mohammed Taghi</creator><creator>Shekaari, Hemayat</creator><general>American Chemical Society</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20050901</creationdate><title>Volumetric and Speed of Sound of Ionic Liquid, 1-Butyl-3-methylimidazolium Hexafluorophosphate with Acetonitrile and Methanol at T = (298.15 to 318.15) K</title><author>Zafarani-Moattar, Mohammed Taghi ; Shekaari, Hemayat</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a327t-72e21d79b6a59f661e33ffaf432df3485a846c1e4dc641b7bc21f84d91021cd73</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2005</creationdate><topic>Chemical thermodynamics</topic><topic>Chemistry</topic><topic>Exact sciences and technology</topic><topic>General and physical chemistry</topic><topic>Mixtures</topic><topic>Thermodynamic properties</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zafarani-Moattar, Mohammed Taghi</creatorcontrib><creatorcontrib>Shekaari, Hemayat</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><jtitle>Journal of chemical and engineering data</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zafarani-Moattar, Mohammed Taghi</au><au>Shekaari, Hemayat</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Volumetric and Speed of Sound of Ionic Liquid, 1-Butyl-3-methylimidazolium Hexafluorophosphate with Acetonitrile and Methanol at T = (298.15 to 318.15) K</atitle><jtitle>Journal of chemical and engineering data</jtitle><addtitle>J. Chem. Eng. Data</addtitle><date>2005-09-01</date><risdate>2005</risdate><volume>50</volume><issue>5</issue><spage>1694</spage><epage>1699</epage><pages>1694-1699</pages><issn>0021-9568</issn><eissn>1520-5134</eissn><coden>JCEAAX</coden><abstract>We report the density (ρ) and speed of sound (u) data for 1-butyl-3-methylimidazolium hexafluorophosphate ([BMIM][PF6]) + methanol and ([BMIM][PF6]) + acetonitrile binary mixtures over the entire range of their compositions at T = (298.15 to 318.15) K. From these data, excess molar volume and isentropic compressibility deviation values have been calculated and fitted to the fourth-order Redlich−Kister equation. The excess molar volume values (V E) for acetonitrile mixtures are more negative than methanol mixtures. Isentropic compressibility deviation values (Δκs) in methanol mixtures are more than acetonitrile mixtures. The results have been interpreted in terms of ion−dipole interactions and structural factors of the ionic liquid and these organic solvents.</abstract><cop>Washington, DC</cop><pub>American Chemical Society</pub><doi>10.1021/je050165t</doi><tpages>6</tpages></addata></record>
fulltext fulltext
identifier ISSN: 0021-9568
ispartof Journal of chemical and engineering data, 2005-09, Vol.50 (5), p.1694-1699
issn 0021-9568
1520-5134
language eng
recordid cdi_crossref_primary_10_1021_je050165t
source ACS Publications
subjects Chemical thermodynamics
Chemistry
Exact sciences and technology
General and physical chemistry
Mixtures
Thermodynamic properties
title Volumetric and Speed of Sound of Ionic Liquid, 1-Butyl-3-methylimidazolium Hexafluorophosphate with Acetonitrile and Methanol at T = (298.15 to 318.15) K
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-11T03%3A59%3A24IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-istex_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Volumetric%20and%20Speed%20of%20Sound%20of%20Ionic%20Liquid,%201-Butyl-3-methylimidazolium%20Hexafluorophosphate%20with%20Acetonitrile%20and%20Methanol%20at%20T%20=%20(298.15%20to%20318.15)%20K&rft.jtitle=Journal%20of%20chemical%20and%20engineering%20data&rft.au=Zafarani-Moattar,%20Mohammed%20Taghi&rft.date=2005-09-01&rft.volume=50&rft.issue=5&rft.spage=1694&rft.epage=1699&rft.pages=1694-1699&rft.issn=0021-9568&rft.eissn=1520-5134&rft.coden=JCEAAX&rft_id=info:doi/10.1021/je050165t&rft_dat=%3Cistex_cross%3Eark_67375_TPS_S9T8ZTKS_4%3C/istex_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true