Triple-Kagomé-Layer Slabs of Mixed-Valence Rare-Earth Ions Exhibiting Quantum Spin Liquid Behaviors: Synthesis and Characterization of Eu 9 MgS 2 B 20 O 41

Triple-Kagomé-Layer Slabs of Mixed-Valence Rare-Earth Ions Exhibiting Quantum Spin Liquid Behaviors: Synthesis and Characterization of Eu 9 MgS 2 B 20 O 41

We prepared a new rare-earth compound, Eu MgS B O (EMSBO), and characterized its structural and physical properties. EMSBO consists of triple-Kagomé-layer slabs separated by nonmagnetic ions and groups. Within each slab, intervalence charge transfer has been found to occur between the Eu and Eu Kago...

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Veröffentlicht in:Journal of the American Chemical Society 2019-06, Vol.141 (24), p.9533-9536
Hauptverfasser: Chi, Yang, Xu, Jing, Xue, Huai-Guo, Zhang, Yueping, Chen, Xiaolong, Whangbo, Myung-Hwan, Guo, Sheng-Ping, Deng, Shuiquan
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container_end_page 9536
container_issue 24
container_start_page 9533
container_title Journal of the American Chemical Society
container_volume 141
creator Chi, Yang
Xu, Jing
Xue, Huai-Guo
Zhang, Yueping
Chen, Xiaolong
Whangbo, Myung-Hwan
Guo, Sheng-Ping
Deng, Shuiquan
description We prepared a new rare-earth compound, Eu MgS B O (EMSBO), and characterized its structural and physical properties. EMSBO consists of triple-Kagomé-layer slabs separated by nonmagnetic ions and groups. Within each slab, intervalence charge transfer has been found to occur between the Eu and Eu Kagomé layers, a new channel for quantum fluctuation of magnetic moments. The measured magnetic susceptibilities and the specific heat capacity exhibit very similar features characteristic of quantum spin liquid behaviors observed in other materials.
doi_str_mv 10.1021/jacs.9b04627
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title Triple-Kagomé-Layer Slabs of Mixed-Valence Rare-Earth Ions Exhibiting Quantum Spin Liquid Behaviors: Synthesis and Characterization of Eu 9 MgS 2 B 20 O 41
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