α‑Sulfinyl Benzoates as Precursors to Li and Mg Carbenoids for the Stereoselective Iterative Homologation of Boronic Esters

The stereoselective reagent-controlled homologation of boronic esters is one of a small number of iteratable synthetic transformations that if automated could form the basis of a veritable molecule-making machine. Recently, α-stannyl triisopropylbenzoates and α-sulfinyl chlorides have emerged as use...

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Veröffentlicht in:	Journal of the American Chemical Society 2017-08, Vol.139 (34), p.11877-11886
Hauptverfasser:	Casoni, Giorgia, Kucukdisli, Murat, Fordham, James M, Burns, Matthew, Myers, Eddie L, Aggarwal, Varinder K
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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