A-Site and B-Site Charge Orderings in an s-d Level Controlled Perovskite Oxide PbCoO 3
Perovskite PbCoO synthesized at 12 GPa was found to have an unusual charge distribution of Pb Pb Co Co O with charge orderings in both the A and B sites of perovskite ABO . Comprehensive studies using density functional theory (DFT) calculation, electron diffraction (ED), synchrotron X-ray diffracti...
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| Veröffentlicht in: | Journal of the American Chemical Society 2017-03, Vol.139 (12), p.4574-4581 |
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| creator | Sakai, Yuki Yang, Junye Yu, Runze Hojo, Hajime Yamada, Ikuya Miao, Ping Lee, Sanghyun Torii, Shuki Kamiyama, Takashi Ležaić, Marjana Bihlmayer, Gustav Mizumaki, Masaichiro Komiyama, Jun Mizokawa, Takashi Yamamoto, Hajime Nishikubo, Takumi Hattori, Yuichiro Oka, Kengo Yin, Yunyu Dai, Jianhong Li, Wenmin Ueda, Shigenori Aimi, Akihisa Mori, Daisuke Inaguma, Yoshiyuki Hu, Zhiwei Uozumi, Takayuki Jin, Changqing Long, Youwen Azuma, Masaki |
| description | Perovskite PbCoO
synthesized at 12 GPa was found to have an unusual charge distribution of Pb
Pb
Co
Co
O
with charge orderings in both the A and B sites of perovskite ABO
. Comprehensive studies using density functional theory (DFT) calculation, electron diffraction (ED), synchrotron X-ray diffraction (SXRD), neutron powder diffraction (NPD), hard X-ray photoemission spectroscopy (HAXPES), soft X-ray absorption spectroscopy (XAS), and measurements of specific heat as well as magnetic and electrical properties provide evidence of lead ion and cobalt ion charge ordering leading to Pb
Pb
Co
Co
O
quadruple perovskite structure. It is shown that the average valence distribution of Pb
Co
O
between Pb
Cr
O
and Pb
Ni
O
can be stabilized by tuning the energy levels of Pb 6s and transition metal 3d orbitals. |
| doi_str_mv | 10.1021/jacs.7b01851 |
| format | Article |
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synthesized at 12 GPa was found to have an unusual charge distribution of Pb
Pb
Co
Co
O
with charge orderings in both the A and B sites of perovskite ABO
. Comprehensive studies using density functional theory (DFT) calculation, electron diffraction (ED), synchrotron X-ray diffraction (SXRD), neutron powder diffraction (NPD), hard X-ray photoemission spectroscopy (HAXPES), soft X-ray absorption spectroscopy (XAS), and measurements of specific heat as well as magnetic and electrical properties provide evidence of lead ion and cobalt ion charge ordering leading to Pb
Pb
Co
Co
O
quadruple perovskite structure. It is shown that the average valence distribution of Pb
Co
O
between Pb
Cr
O
and Pb
Ni
O
can be stabilized by tuning the energy levels of Pb 6s and transition metal 3d orbitals.</description><identifier>ISSN: 0002-7863</identifier><identifier>EISSN: 1520-5126</identifier><identifier>DOI: 10.1021/jacs.7b01851</identifier><identifier>PMID: 28240901</identifier><language>eng</language><publisher>United States</publisher><ispartof>Journal of the American Chemical Society, 2017-03, Vol.139 (12), p.4574-4581</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c1031-304dec30ffd800ea02616f40fce22c4913e4574cb933308aec2f27f0bd9f27383</citedby><cites>FETCH-LOGICAL-c1031-304dec30ffd800ea02616f40fce22c4913e4574cb933308aec2f27f0bd9f27383</cites><orcidid>0000-0003-2340-131X ; 0000-0002-7682-2348 ; 0000-0002-8378-321X ; 0000-0002-8587-7818</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,2765,27924,27925</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/28240901$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Sakai, Yuki</creatorcontrib><creatorcontrib>Yang, Junye</creatorcontrib><creatorcontrib>Yu, Runze</creatorcontrib><creatorcontrib>Hojo, Hajime</creatorcontrib><creatorcontrib>Yamada, Ikuya</creatorcontrib><creatorcontrib>Miao, Ping</creatorcontrib><creatorcontrib>Lee, Sanghyun</creatorcontrib><creatorcontrib>Torii, Shuki</creatorcontrib><creatorcontrib>Kamiyama, Takashi</creatorcontrib><creatorcontrib>Ležaić, Marjana</creatorcontrib><creatorcontrib>Bihlmayer, Gustav</creatorcontrib><creatorcontrib>Mizumaki, Masaichiro</creatorcontrib><creatorcontrib>Komiyama, Jun</creatorcontrib><creatorcontrib>Mizokawa, Takashi</creatorcontrib><creatorcontrib>Yamamoto, Hajime</creatorcontrib><creatorcontrib>Nishikubo, Takumi</creatorcontrib><creatorcontrib>Hattori, Yuichiro</creatorcontrib><creatorcontrib>Oka, Kengo</creatorcontrib><creatorcontrib>Yin, Yunyu</creatorcontrib><creatorcontrib>Dai, Jianhong</creatorcontrib><creatorcontrib>Li, Wenmin</creatorcontrib><creatorcontrib>Ueda, Shigenori</creatorcontrib><creatorcontrib>Aimi, Akihisa</creatorcontrib><creatorcontrib>Mori, Daisuke</creatorcontrib><creatorcontrib>Inaguma, Yoshiyuki</creatorcontrib><creatorcontrib>Hu, Zhiwei</creatorcontrib><creatorcontrib>Uozumi, Takayuki</creatorcontrib><creatorcontrib>Jin, Changqing</creatorcontrib><creatorcontrib>Long, Youwen</creatorcontrib><creatorcontrib>Azuma, Masaki</creatorcontrib><title>A-Site and B-Site Charge Orderings in an s-d Level Controlled Perovskite Oxide PbCoO 3</title><title>Journal of the American Chemical Society</title><addtitle>J Am Chem Soc</addtitle><description>Perovskite PbCoO
synthesized at 12 GPa was found to have an unusual charge distribution of Pb
Pb
Co
Co
O
with charge orderings in both the A and B sites of perovskite ABO
. Comprehensive studies using density functional theory (DFT) calculation, electron diffraction (ED), synchrotron X-ray diffraction (SXRD), neutron powder diffraction (NPD), hard X-ray photoemission spectroscopy (HAXPES), soft X-ray absorption spectroscopy (XAS), and measurements of specific heat as well as magnetic and electrical properties provide evidence of lead ion and cobalt ion charge ordering leading to Pb
Pb
Co
Co
O
quadruple perovskite structure. It is shown that the average valence distribution of Pb
Co
O
between Pb
Cr
O
and Pb
Ni
O
can be stabilized by tuning the energy levels of Pb 6s and transition metal 3d orbitals.</description><issn>0002-7863</issn><issn>1520-5126</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><recordid>eNo9kMtOwzAQRS0EoqWwY438AbiMH0mcZYl4SZVSicc2cuxxSUmTyoYK_p5ULazujO6ZWRxCLjlMOQh-szI2TrMauE74ERnzRABLuEiPyRgABMt0KkfkLMbVsCqh-SkZCS0U5MDH5G3GnptPpKZz9HY_Fu8mLJGWwWFoumWkTTfUNDJH57jFlhZ99xn6tkVHFxj6bfzYnZXfjUO6qIu-pPKcnHjTRrw45IS83t-9FI9sXj48FbM5sxwkZxKUQyvBe6cB0IBIeeoVeItCWJVziSrJlK1zKSVog1Z4kXmoXT6k1HJCrvd_behjDOirTWjWJvxUHKqdnmqnpzroGfCrPb75qtfo_uE_H_IXWfFewg</recordid><startdate>20170329</startdate><enddate>20170329</enddate><creator>Sakai, Yuki</creator><creator>Yang, Junye</creator><creator>Yu, Runze</creator><creator>Hojo, Hajime</creator><creator>Yamada, Ikuya</creator><creator>Miao, Ping</creator><creator>Lee, Sanghyun</creator><creator>Torii, Shuki</creator><creator>Kamiyama, Takashi</creator><creator>Ležaić, Marjana</creator><creator>Bihlmayer, Gustav</creator><creator>Mizumaki, Masaichiro</creator><creator>Komiyama, Jun</creator><creator>Mizokawa, Takashi</creator><creator>Yamamoto, Hajime</creator><creator>Nishikubo, Takumi</creator><creator>Hattori, Yuichiro</creator><creator>Oka, Kengo</creator><creator>Yin, Yunyu</creator><creator>Dai, Jianhong</creator><creator>Li, Wenmin</creator><creator>Ueda, Shigenori</creator><creator>Aimi, Akihisa</creator><creator>Mori, Daisuke</creator><creator>Inaguma, Yoshiyuki</creator><creator>Hu, Zhiwei</creator><creator>Uozumi, Takayuki</creator><creator>Jin, Changqing</creator><creator>Long, Youwen</creator><creator>Azuma, Masaki</creator><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0003-2340-131X</orcidid><orcidid>https://orcid.org/0000-0002-7682-2348</orcidid><orcidid>https://orcid.org/0000-0002-8378-321X</orcidid><orcidid>https://orcid.org/0000-0002-8587-7818</orcidid></search><sort><creationdate>20170329</creationdate><title>A-Site and B-Site Charge Orderings in an s-d Level Controlled Perovskite Oxide PbCoO 3</title><author>Sakai, Yuki ; Yang, Junye ; Yu, Runze ; Hojo, Hajime ; Yamada, Ikuya ; Miao, Ping ; Lee, Sanghyun ; Torii, Shuki ; Kamiyama, Takashi ; Ležaić, Marjana ; Bihlmayer, Gustav ; Mizumaki, Masaichiro ; Komiyama, Jun ; Mizokawa, Takashi ; Yamamoto, Hajime ; Nishikubo, Takumi ; Hattori, Yuichiro ; Oka, Kengo ; Yin, Yunyu ; Dai, Jianhong ; Li, Wenmin ; Ueda, Shigenori ; Aimi, Akihisa ; Mori, Daisuke ; Inaguma, Yoshiyuki ; Hu, Zhiwei ; Uozumi, Takayuki ; Jin, Changqing ; Long, Youwen ; Azuma, Masaki</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c1031-304dec30ffd800ea02616f40fce22c4913e4574cb933308aec2f27f0bd9f27383</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Sakai, Yuki</creatorcontrib><creatorcontrib>Yang, Junye</creatorcontrib><creatorcontrib>Yu, Runze</creatorcontrib><creatorcontrib>Hojo, Hajime</creatorcontrib><creatorcontrib>Yamada, Ikuya</creatorcontrib><creatorcontrib>Miao, Ping</creatorcontrib><creatorcontrib>Lee, Sanghyun</creatorcontrib><creatorcontrib>Torii, Shuki</creatorcontrib><creatorcontrib>Kamiyama, Takashi</creatorcontrib><creatorcontrib>Ležaić, Marjana</creatorcontrib><creatorcontrib>Bihlmayer, Gustav</creatorcontrib><creatorcontrib>Mizumaki, Masaichiro</creatorcontrib><creatorcontrib>Komiyama, Jun</creatorcontrib><creatorcontrib>Mizokawa, Takashi</creatorcontrib><creatorcontrib>Yamamoto, Hajime</creatorcontrib><creatorcontrib>Nishikubo, Takumi</creatorcontrib><creatorcontrib>Hattori, Yuichiro</creatorcontrib><creatorcontrib>Oka, Kengo</creatorcontrib><creatorcontrib>Yin, Yunyu</creatorcontrib><creatorcontrib>Dai, Jianhong</creatorcontrib><creatorcontrib>Li, Wenmin</creatorcontrib><creatorcontrib>Ueda, Shigenori</creatorcontrib><creatorcontrib>Aimi, Akihisa</creatorcontrib><creatorcontrib>Mori, Daisuke</creatorcontrib><creatorcontrib>Inaguma, Yoshiyuki</creatorcontrib><creatorcontrib>Hu, Zhiwei</creatorcontrib><creatorcontrib>Uozumi, Takayuki</creatorcontrib><creatorcontrib>Jin, Changqing</creatorcontrib><creatorcontrib>Long, Youwen</creatorcontrib><creatorcontrib>Azuma, Masaki</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><jtitle>Journal of the American Chemical Society</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Sakai, Yuki</au><au>Yang, Junye</au><au>Yu, Runze</au><au>Hojo, Hajime</au><au>Yamada, Ikuya</au><au>Miao, Ping</au><au>Lee, Sanghyun</au><au>Torii, Shuki</au><au>Kamiyama, Takashi</au><au>Ležaić, Marjana</au><au>Bihlmayer, Gustav</au><au>Mizumaki, Masaichiro</au><au>Komiyama, Jun</au><au>Mizokawa, Takashi</au><au>Yamamoto, Hajime</au><au>Nishikubo, Takumi</au><au>Hattori, Yuichiro</au><au>Oka, Kengo</au><au>Yin, Yunyu</au><au>Dai, Jianhong</au><au>Li, Wenmin</au><au>Ueda, Shigenori</au><au>Aimi, Akihisa</au><au>Mori, Daisuke</au><au>Inaguma, Yoshiyuki</au><au>Hu, Zhiwei</au><au>Uozumi, Takayuki</au><au>Jin, Changqing</au><au>Long, Youwen</au><au>Azuma, Masaki</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A-Site and B-Site Charge Orderings in an s-d Level Controlled Perovskite Oxide PbCoO 3</atitle><jtitle>Journal of the American Chemical Society</jtitle><addtitle>J Am Chem Soc</addtitle><date>2017-03-29</date><risdate>2017</risdate><volume>139</volume><issue>12</issue><spage>4574</spage><epage>4581</epage><pages>4574-4581</pages><issn>0002-7863</issn><eissn>1520-5126</eissn><abstract>Perovskite PbCoO
synthesized at 12 GPa was found to have an unusual charge distribution of Pb
Pb
Co
Co
O
with charge orderings in both the A and B sites of perovskite ABO
. Comprehensive studies using density functional theory (DFT) calculation, electron diffraction (ED), synchrotron X-ray diffraction (SXRD), neutron powder diffraction (NPD), hard X-ray photoemission spectroscopy (HAXPES), soft X-ray absorption spectroscopy (XAS), and measurements of specific heat as well as magnetic and electrical properties provide evidence of lead ion and cobalt ion charge ordering leading to Pb
Pb
Co
Co
O
quadruple perovskite structure. It is shown that the average valence distribution of Pb
Co
O
between Pb
Cr
O
and Pb
Ni
O
can be stabilized by tuning the energy levels of Pb 6s and transition metal 3d orbitals.</abstract><cop>United States</cop><pmid>28240901</pmid><doi>10.1021/jacs.7b01851</doi><tpages>8</tpages><orcidid>https://orcid.org/0000-0003-2340-131X</orcidid><orcidid>https://orcid.org/0000-0002-7682-2348</orcidid><orcidid>https://orcid.org/0000-0002-8378-321X</orcidid><orcidid>https://orcid.org/0000-0002-8587-7818</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0002-7863 |
| ispartof | Journal of the American Chemical Society, 2017-03, Vol.139 (12), p.4574-4581 |
| issn | 0002-7863 1520-5126 |
| language | eng |
| recordid | cdi_crossref_primary_10_1021_jacs_7b01851 |
| source | ACS Publications |
| title | A-Site and B-Site Charge Orderings in an s-d Level Controlled Perovskite Oxide PbCoO 3 |
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