Alkyne Semihydrogenation with a Well-Defined Nonclassical Co-H 2 Catalyst: A H 2 Spin on Isomerization and E-Selectivity

The reactivity of a Co -H complex was extended toward the semihydrogenation of internal alkynes. Under ambient temperatures and moderate pressures of H , a broad scope of alkynes were semihydrogenated using a Co -N precatalyst, resulting in the formation of trans-alkene products. Furthermore, mechan...

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Veröffentlicht in:	Journal of the American Chemical Society 2016-10, Vol.138 (41), p.13700-13705
Hauptverfasser:	Tokmic, Kenan, Fout, Alison R
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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