Interplay of Stereochemistry and Charge Governs Guest Binding in Flexible Zn II 4 L 4 Cages

Here, we report the synthesis of a family of chiral Zn L tetrahedral cages by subcomponent self-assembly. These cages contain a flexible trialdehyde subcomponent that allows them to adopt stereochemically distinct configurations. The incorporation of enantiopure 1-phenylethylamine produced Δ and Λ e...

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Veröffentlicht in:	Journal of the American Chemical Society 2024-11, Vol.146 (47), p.32730-32737
Hauptverfasser:	Xue, Weichao, Benchimol, Elie, Walther, Alexandre, Ouyang, Nianfeng, Holstein, Julian J, Ronson, Tanya K, Openy, Joseph, Zhou, Yujuan, Wu, Kai, Chowdhury, Rituparno, Clever, Guido H, Nitschke, Jonathan R
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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