Uncovering Redox Non-innocent Hydrogen-Bonding in Cu(I)-Diazene Complexes

The life-sustaining reduction of N2 to NH3 is thermoneutral yet kinetically challenged by high-energy intermediates such as N2H2. Exploring intramolecular H-bonding as a potential strategy to stabilize diazene intermediates, we employ a series of [ xHetTpCu]2(μ-N2H2) complexes that exhibit H-bonding...

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	Journal of the American Chemical Society 2021-10, Vol.143 (39), p.15960-15974
Hauptverfasser:	Gardner, Evan J, Marguet, Sean C, Cobb, Caitlyn R, Pham, Dominic M, Beringer, Josalyne A. M, Bertke, Jeffery A, Shafaat, Hannah S, Warren, Timothy H
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Chemistry, Multidisciplinary Physical Sciences Science & Technology
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!