One Site, Two Cations, Three Environments: s 2 and s 0 Electronic Configurations Generate Pb-Free Relaxor Behavior in a Perovskite Oxide

The piezoelectric devices widespread in society use noncentrosymmetric Pb-based oxides because of their outstanding functional properties. The highest figures of merit reported are for perovskites based on the parent Pb(Mg Nb )O (PMN), which is a relaxor: a centrosymmetric material with local symmet...

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Veröffentlicht in:Journal of the American Chemical Society 2021-01, Vol.143 (3), p.1386-1398
Hauptverfasser: Surta, T Wesley, Whittle, Thomas A, Wright, Matthew A, Niu, Hongjun, Gamon, Jacinthe, Gibson, Quinn D, Daniels, Luke M, Thomas, William J, Zanella, Marco, Shepley, Philippa M, Li, Yang, Goetzee-Barral, Anton, Bell, Andrew J, Alaria, Jonathan, Claridge, John B, Rosseinsky, Matthew J
Format: Artikel
Sprache:eng
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