Cyclic (Amino)(aryl)carbenes Enter the Field of Chromophore Ligands: Expanded π System Leads to Unusually Deep Red Emitting Cu I Compounds

A series of copper(I) complexes bearing a cyclic (amino)(aryl)carbene (CAArC) ligand with various complex geometries have been investigated in great detail with regard to their structural, electronic, and photophysical properties. Comparison of [CuX(CAArC)] (X = Br ( ), Cbz ( ), acac ( ), Ph acac (...

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Veröffentlicht in:	Journal of the American Chemical Society 2020-05, Vol.142 (19), p.8897-8909
Hauptverfasser:	Gernert, Markus, Balles-Wolf, Lukas, Kerner, Florian, Müller, Ulrich, Schmiedel, Alexander, Holzapfel, Marco, Marian, Christel M, Pflaum, Jens, Lambert, Christoph, Steffen, Andreas
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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