Acetylene Cyclotrimerization on Supported Size-Selected Pd n Clusters (1 ≤ n ≤ 30): One Atom Is Enough

We studied the cyclotrimerization of acetylene on size-selected Pd n clusters (1 ≤ n ≤ 30) supported on thin MgO(100) films by thermal desorption and Fourier transform infrared spectroscopy. Surprisingly, the production of benzene is already observed on a single palladium atom at low temperature (30...

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Veröffentlicht in:	Journal of the American Chemical Society 2000-04, Vol.122 (14), p.3453-3457
Hauptverfasser:	Abbet, S, Sanchez, A, Heiz, U, Schneider, W.-D, Ferrari, A. M, Pacchioni, G, Rösch, N
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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