Structure−Reactivity Relationships in Radical Reactions:  A Novel Method for the Simultaneous Determination of Absolute Rate Constants and Structural Features

Analysis of the ESR line width in time-resolved (TR-ESR) experiments is shown to be a suitable tool for the measurement of addition constants of phosphinoyl and substituted benzoyl radicals. Compared with kinetic investigations, which make use of the resonance intensity or integral, observation of t...

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Veröffentlicht in:	Journal of the American Chemical Society 1999-09, Vol.121 (36), p.8332-8336
Hauptverfasser:	Gatlik, Iwo, Rzadek, Piotr, Gescheidt, Georg, Rist, Günther, Hellrung, Bruno, Wirz, Jakob, Dietliker, Kurt, Hug, Gebhard, Kunz, Martin, Wolf, Jean-Pierre
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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