One- and Two-Electron Oxidative Pathways Leading to Cyclopropane-Containing Oxidized Porphyrinogens and C−C-Coupled Porphyrinogens from Alkali Cation− and Transition Metal−meso-Octaethylporphyrinogen Complexes

This report deals with the different transition metal- and alkali cation-assisted oxidation pathways of the meso-octaethylporphyrinogen tetraanion [Et8N4]4-. The two-electron oxidation of [Et8N4Mn{Na(thf)2}2], 4, with Cp2FeBPh4 led to the corresponding monocyclopropane derivative [Et8N4(Δ)Mn], 6, [Δ...

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Veröffentlicht in:	Journal of the American Chemical Society 1999-03, Vol.121 (8), p.1695-1706
Hauptverfasser:	Crescenzi, Raffaella, Solari, Euro, Floriani, Carlo, Chiesi-Villa, Angiola, Rizzoli, Corrado
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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