Design of Brønsted Acid-Assisted Chiral Lewis Acid (BLA) Catalysts for Highly Enantioselective Diels−Alder Reactions

Brønsted acid-assisted chiral Lewis acid (BLA) was highly effective as a chiral catalyst for the enantioselective Diels−Alder reaction of both α-substituted and α-unsubstituted α,β-enals with various dienes. Hydroxy groups in optically active binaphthol derivatives and boron reagents with electron-w...

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Veröffentlicht in:Journal of the American Chemical Society 1998-07, Vol.120 (28), p.6920-6930
Hauptverfasser: Ishihara, Kazuaki, Kurihara, Hideki, Matsumoto, Masayuki, Yamamoto, Hisashi
Format: Artikel
Sprache:eng
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