“New” Catalysts for the Ester-Interchange Reaction:  The Role of Alkali-Metal Alkoxide Clusters in Achieving Unprecedented Reaction Rates

The catalytic effect of alkali-metal tert-butoxide clusters on the rate of ester interchange for several pairs of esters has been determined in nonpolar and weakly polar solvents. Reactivities increase in the order (Li+ < Na+ < K+ < Rb+ < Cs+) with the fastest rates reaching 107 catalyti...

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Veröffentlicht in:	Journal of the American Chemical Society 1998-06, Vol.120 (24), p.5981-5989
Hauptverfasser:	Stanton, Matthew G, Allen, Cara B, Kissling, Rebecca M, Lincoln, Alice L, Gagné, Michel R
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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