Reactions of Ground-State Ti+ and V+ with Propane:  Factors That Govern C−H and C−C Bond Cleavage Product Branching Ratios

Reactions of Ti+ and V+ with C3H8, CH3CD2CH3, CD3CH2CD3, and C3D8 are studied to characterize the rate-limiting transition states and determine the factors that control the branching between H2 and CH4 elimination. For ground-state Ti+ reacting with propane, dehydrogenation and demethanation both oc...

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Veröffentlicht in:	Journal of the American Chemical Society 1998-06, Vol.120 (23), p.5704-5712
Hauptverfasser:	van Koppen, Petra A. M, Bowers, Michael T, Haynes, Chris L, Armentrout, P. B
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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