Molecular Oxygen Activation by a Ruthenium-Substituted “Sandwich” Type Polyoxometalate
The ruthenium-substituted “sandwich” type polyoxometalate [WZnRuIII 2(XW9O34)2]11- where X = ZnII or CoII has been shown to be unique in its ability to catalyze the selective hydroxylation of adamantane at the tertiary carbon position with molecular oxygen as the oxygen donor. The hydroxylation feat...
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| Veröffentlicht in: | Journal of the American Chemical Society 1998-11, Vol.120 (46), p.11969-11976 |
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| Hauptverfasser: | , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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