Synthesis of Optically Active α-Hydroxy Carbonyl Compounds by the Catalytic, Enantioselective Oxidation of Silyl Enol Ethers and Ketene Acetals with (Salen)manganese(III) Complexes

A set of silyl enol ethers and ketene acetals 1a − h with α- and/or β-phenyl as well as alkyl substituents of different steric bulk has been submitted to the enantioselective catalytic oxidation by chiral (salen)MnIII complexes 3. Highest conversions and best enantioselectivities have been obtained...

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Veröffentlicht in:	Journal of the American Chemical Society 1998-02, Vol.120 (4), p.708-714
Hauptverfasser:	Adam, Waldemar, Fell, Rainer T, Stegmann, Veit R, Saha-Möller, Chantu R
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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