Unimolecular Electrical Rectification in Hexadecylquinolinium Tricyanoquinodimethanide
Macroscopic and nanoscopic current−voltage measurements reveal asymmetries in the DC electrical conductivity through Langmuir−Blodgett multilayers and even monolayers of γ-(n-hexadecyl)quinolinum tricyanoquinodimethanide, C16H33Q-3CNQ (5). These asymmetries are due to a transition of the ground-stat...
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| Veröffentlicht in: | Journal of the American Chemical Society 1997-10, Vol.119 (43), p.10455-10466 |
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| container_issue | 43 |
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| container_title | Journal of the American Chemical Society |
| container_volume | 119 |
| creator | Metzger, Robert M Chen, Bo Höpfner, Ulf Lakshmikantham, M. V Vuillaume, Dominique Kawai, Tsuyoshi Wu, Xiangli Tachibana, Hiroaki Hughes, Terry V Sakurai, Hiromi Baldwin, Jeffrey W Hosch, Christina Cava, Michael P Brehmer, Ludwig Ashwell, Geoffrey J |
| description | Macroscopic and nanoscopic current−voltage measurements reveal asymmetries in the DC electrical conductivity through Langmuir−Blodgett multilayers and even monolayers of γ-(n-hexadecyl)quinolinum tricyanoquinodimethanide, C16H33Q-3CNQ (5). These asymmetries are due to a transition of the ground-state zwitterion to an excited-state conformer which is probably neutral. Unimolecular electrical rectification by monolayers of 5 is unequivocally confirmed. |
| doi_str_mv | 10.1021/ja971811e |
| format | Article |
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V ; Vuillaume, Dominique ; Kawai, Tsuyoshi ; Wu, Xiangli ; Tachibana, Hiroaki ; Hughes, Terry V ; Sakurai, Hiromi ; Baldwin, Jeffrey W ; Hosch, Christina ; Cava, Michael P ; Brehmer, Ludwig ; Ashwell, Geoffrey J</creator><creatorcontrib>Metzger, Robert M ; Chen, Bo ; Höpfner, Ulf ; Lakshmikantham, M. V ; Vuillaume, Dominique ; Kawai, Tsuyoshi ; Wu, Xiangli ; Tachibana, Hiroaki ; Hughes, Terry V ; Sakurai, Hiromi ; Baldwin, Jeffrey W ; Hosch, Christina ; Cava, Michael P ; Brehmer, Ludwig ; Ashwell, Geoffrey J</creatorcontrib><description>Macroscopic and nanoscopic current−voltage measurements reveal asymmetries in the DC electrical conductivity through Langmuir−Blodgett multilayers and even monolayers of γ-(n-hexadecyl)quinolinum tricyanoquinodimethanide, C16H33Q-3CNQ (5). These asymmetries are due to a transition of the ground-state zwitterion to an excited-state conformer which is probably neutral. 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These asymmetries are due to a transition of the ground-state zwitterion to an excited-state conformer which is probably neutral. Unimolecular electrical rectification by monolayers of 5 is unequivocally confirmed.</abstract><pub>American Chemical Society</pub><doi>10.1021/ja971811e</doi><tpages>12</tpages></addata></record> |
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| source | ACS Publications |
| title | Unimolecular Electrical Rectification in Hexadecylquinolinium Tricyanoquinodimethanide |
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