Magnetic Circular Dichroism Spectroscopy as a Probe of Geometric and Electronic Structure of Cobalt(II)-Substituted Proteins:  Ground-State Zero-Field Splitting as a Coordination Number Indicator

Variable-temperature magnetic circular dichroism (VT MCD) is used as a probe of the ground-state electronic structure in Co(II)-substituted liver alcohol dehyrogenase, carbonic anhydrase, carboxypeptidase, substrate and inhibitor complexes of these enzymes, and four- and five-coordinate Co(II) model...

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Veröffentlicht in:	Journal of the American Chemical Society 1997-05, Vol.119 (18), p.4182-4196
Hauptverfasser:	Larrabee, James A, Alessi, Christopher M, Asiedu, Esi T, Cook, Justin O, Hoerning, Keith R, Klingler, Lance J, Okin, Gregory S, Santee, Stuart G, Volkert, Thomas L
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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