Rhenium Dihydrogen Complexes with Isonitrile Coligands:  Novel Displacement of Chloride by Hydrogen

The syntheses, properties, and characterization of several new complexes, Re(CNtBu)3(PCy3)2H (1a), Re(CNtBu)3(PR3)2Cl [R = Cy, Ph (2a, 2b)], the 17-electron [Re(CNtBu)3(PCy3)2Cl]+ (3a), the dihydrogen complex, [Re(CNtBu)3(PR3)2(H2)]+ [R = Cy, Ph (4a, 4b)], the coordinatively unsaturated [Re(CNtBu)3(...

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	Journal of the American Chemical Society 1996-11, Vol.118 (44), p.10792-10802
Hauptverfasser:	Heinekey, D. M, Voges, Mark H, Barnhart, David M
Format:	Artikel
Sprache:	eng
Schlagworte:	40 CHEMISTRY CHEMICAL BONDS CHLORIDES CRYSTALLOGRAPHY HYDROGEN LIGANDS MOLECULAR STRUCTURE NUCLEAR MAGNETIC RESONANCE NUMERICAL DATA PHYSICS RHENIUM COMPOUNDS SYNTHESIS TEMPERATURE DEPENDENCE X-RAY DIFFRACTION
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!