Fluorophobic Effect Induces the Self-Assembly of Semifluorinated Tapered Monodendrons Containing Crown Ethers into Supramolecular Columnar Dendrimers Which Exhibit a Homeotropic Hexagonal Columnar Liquid Crystalline Phase

The rational design, synthesis, and characterization of the building blocks obtained by the esterification of the first generation of tapered monodendrons 3,4,5-tris(p-dodecan-1-yloxy)benzoic acid (12-AG) and 3,4,5-tris[p-(n-dodecan-1-yloxy)benzyloxy]benzoic acid (12-ABG) containing semifluorinated...

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Veröffentlicht in:Journal of the American Chemical Society 1996-10, Vol.118 (41), p.9855-9866
Hauptverfasser: Percec, Virgil, Johansson, Gary, Ungar, Goran, Zhou, Jianping
Format: Artikel
Sprache:eng
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