Selective Binding of Group IIIA and Lanthanide Metals by Hexahomotrioxacalix[3]arene Macrocycles
The hexahomotrioxacalix[3]arene macrocycles 1 are observed to bind trivalent metals (Sc3+, Lu3+,Y3+, La3+) more strongly than alkali metal ions (Li+, Na+, K+). Complexes of macrocycle 1a with Lu(III) (3), Y(III) (4), and La(III) (5) have been structurally characterized to be μ-aryloxo-bridged dimers...
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| Veröffentlicht in: | Journal of the American Chemical Society 1996-08, Vol.118 (33), p.7769-7773 |
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| container_issue | 33 |
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| container_title | Journal of the American Chemical Society |
| container_volume | 118 |
| creator | Daitch, Charles E Hampton, Philip D Duesler, Eileen N |
| description | The hexahomotrioxacalix[3]arene macrocycles 1 are observed to bind trivalent metals (Sc3+, Lu3+,Y3+, La3+) more strongly than alkali metal ions (Li+, Na+, K+). Complexes of macrocycle 1a with Lu(III) (3), Y(III) (4), and La(III) (5) have been structurally characterized to be μ-aryloxo-bridged dimers with the formula [M(L)(DMSO)]2 (M = Lu, Y, La; L = trianion of macrocycle 1a). Periodic trends in the structures and dynamic behavior of the complexes are discussed. |
| doi_str_mv | 10.1021/ja9605984 |
| format | Article |
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Complexes of macrocycle 1a with Lu(III) (3), Y(III) (4), and La(III) (5) have been structurally characterized to be μ-aryloxo-bridged dimers with the formula [M(L)(DMSO)]2 (M = Lu, Y, La; L = trianion of macrocycle 1a). 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Periodic trends in the structures and dynamic behavior of the complexes are discussed.</description><subject>40 CHEMISTRY</subject><subject>ACTIVATION ENERGY</subject><subject>CRYSTALLOGRAPHY</subject><subject>LANTHANUM COMPLEXES</subject><subject>LITHIUM COMPLEXES</subject><subject>LUTETIUM COMPLEXES</subject><subject>NMR SPECTRA</subject><subject>ORGANIC COMPOUNDS</subject><subject>POTASSIUM COMPLEXES</subject><subject>SCANDIUM COMPLEXES</subject><subject>SODIUM COMPLEXES</subject><subject>STRUCTURAL CHEMICAL ANALYSIS</subject><subject>SYNTHESIS</subject><subject>YTTRIUM COMPLEXES</subject><issn>0002-7863</issn><issn>1520-5126</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1996</creationdate><recordtype>article</recordtype><recordid>eNpt0EtLAzEQB_AgCtbHwW8QDx48rOaxu2mPKj4qFR_Vk0icTWZtak1Kskr77Y1UPHkaBn7zZ2YI2ePsiDPBj6cwqFk16JdrpMcrwYqKi3qd9BhjolD9Wm6SrZSmuS1Fn_fI6xhnaDr3hfTUeev8Gw0tvYzhc06Hw-EJBW_pCHw3Ae8s0hvsYJZos6RXuIBJ-AhddGEBBmZu8SxfIKLPCkwMZmlmmHbIRpsncPe3bpOni_PHs6tidHs5PDsZFSAF74oSjWDApEILolIKailsaZWRYAGYaSy2VYOiZoIx23LeQDYDKdvWlAobuU32V7khdU4n4zo0ExO8z9dpqcqK8WwOVyZvl1LEVs-j-4C41Jzpn_fpv_dlW6ysSx0u_iDEd10rqSr9eDfWgweh7stxra-zP1h5MElPw2f0-dp_cr8BaBB-Bw</recordid><startdate>19960821</startdate><enddate>19960821</enddate><creator>Daitch, Charles E</creator><creator>Hampton, Philip D</creator><creator>Duesler, Eileen N</creator><general>American Chemical Society</general><scope>BSCLL</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>OTOTI</scope></search><sort><creationdate>19960821</creationdate><title>Selective Binding of Group IIIA and Lanthanide Metals by Hexahomotrioxacalix[3]arene Macrocycles</title><author>Daitch, Charles E ; Hampton, Philip D ; Duesler, Eileen N</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a321t-4ec20a037eda2577a632d4d7c3adaa0cbdef5be260200df11ba7a6933ffc47eb3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1996</creationdate><topic>40 CHEMISTRY</topic><topic>ACTIVATION ENERGY</topic><topic>CRYSTALLOGRAPHY</topic><topic>LANTHANUM COMPLEXES</topic><topic>LITHIUM COMPLEXES</topic><topic>LUTETIUM COMPLEXES</topic><topic>NMR SPECTRA</topic><topic>ORGANIC COMPOUNDS</topic><topic>POTASSIUM COMPLEXES</topic><topic>SCANDIUM COMPLEXES</topic><topic>SODIUM COMPLEXES</topic><topic>STRUCTURAL CHEMICAL ANALYSIS</topic><topic>SYNTHESIS</topic><topic>YTTRIUM COMPLEXES</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Daitch, Charles E</creatorcontrib><creatorcontrib>Hampton, Philip D</creatorcontrib><creatorcontrib>Duesler, Eileen N</creatorcontrib><creatorcontrib>Sandia National Laboratory</creatorcontrib><collection>Istex</collection><collection>CrossRef</collection><collection>OSTI.GOV</collection><jtitle>Journal of the American Chemical Society</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Daitch, Charles E</au><au>Hampton, Philip D</au><au>Duesler, Eileen N</au><aucorp>Sandia National Laboratory</aucorp><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Selective Binding of Group IIIA and Lanthanide Metals by Hexahomotrioxacalix[3]arene Macrocycles</atitle><jtitle>Journal of the American Chemical Society</jtitle><addtitle>J. Am. Chem. Soc</addtitle><date>1996-08-21</date><risdate>1996</risdate><volume>118</volume><issue>33</issue><spage>7769</spage><epage>7773</epage><pages>7769-7773</pages><issn>0002-7863</issn><eissn>1520-5126</eissn><abstract>The hexahomotrioxacalix[3]arene macrocycles 1 are observed to bind trivalent metals (Sc3+, Lu3+,Y3+, La3+) more strongly than alkali metal ions (Li+, Na+, K+). Complexes of macrocycle 1a with Lu(III) (3), Y(III) (4), and La(III) (5) have been structurally characterized to be μ-aryloxo-bridged dimers with the formula [M(L)(DMSO)]2 (M = Lu, Y, La; L = trianion of macrocycle 1a). Periodic trends in the structures and dynamic behavior of the complexes are discussed.</abstract><cop>United States</cop><pub>American Chemical Society</pub><doi>10.1021/ja9605984</doi><tpages>5</tpages></addata></record> |
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| ispartof | Journal of the American Chemical Society, 1996-08, Vol.118 (33), p.7769-7773 |
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| source | American Chemical Society Journals |
| subjects | 40 CHEMISTRY ACTIVATION ENERGY CRYSTALLOGRAPHY LANTHANUM COMPLEXES LITHIUM COMPLEXES LUTETIUM COMPLEXES NMR SPECTRA ORGANIC COMPOUNDS POTASSIUM COMPLEXES SCANDIUM COMPLEXES SODIUM COMPLEXES STRUCTURAL CHEMICAL ANALYSIS SYNTHESIS YTTRIUM COMPLEXES |
| title | Selective Binding of Group IIIA and Lanthanide Metals by Hexahomotrioxacalix[3]arene Macrocycles |
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