Stereoselective Radical Carbon−Carbon Bond Forming Reactions of β-Alkoxy Esters:  Atom and Group Transfer Allylations under Bidentate Chelation Controlled Conditions

The radical allylation of a series of β-alkoxy esters using allyltrimethylsilane in the presence of MgBr2· OEt2 is described. Under bidentate chelation-controlled conditions, allyltrimethylsilane rivals allyltributyltin in efficiency and is a superior reagent from ecological and practical perspectiv...

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Veröffentlicht in:	Journal of the American Chemical Society 1996-12, Vol.118 (50), p.12528-12535
Hauptverfasser:	Guindon, Y, Guérin, B, Chabot, C, Ogilvie, W
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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