Transition Metal-Based Polymers with Controlled Architectures:  Well-Defined Poly(ferrocenylsilane) Homopolymers and Multiblock Copolymers via the Living Anionic Ring-Opening Polymerization of Silicon-Bridged [1]Ferrocenophanes

The living anionic ring-opening polymerization (ROP) of the methylated silicon-bridged [1]ferrocenophane Fe(η-C5H4)2SiMe2 1 initiated by n-BuLi, PhLi, FcLi (Fc = Fe(η-C5H4)(η-C5H5)), and 1,1‘-dilithioferrocene, fcLi2· 2/3TMEDA (fc = Fe(η-C5H4)2) in THF at 20 °C has allowed the preparation of well-de...

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Veröffentlicht in:	Journal of the American Chemical Society 1996-05, Vol.118 (17), p.4102-4114
Hauptverfasser:	Ni, Yizeng, Rulkens, Ron, Manners, Ian
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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