Ultrafast Dynamics of CpM(CO)2 (M = Ir, Rh) in Solution:  The Origin of the Low Quantum Yields for C−H Bond Activation

Using picosecond transient absorption spectroscopy we have examined the dynamics of Cp*Ir(CO)2 (Cp* = C5Me5) in cyclohexane and Cp*Rh(CO)2 in n-pentane solution at room temperature following 295-nm UV excitation. A transient absorption with an instrument limited risetime was observed for Ir from 440...

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Veröffentlicht in:	Journal of the American Chemical Society 1996-02, Vol.118 (8), p.2069-2072
Hauptverfasser:	Bromberg, Steven E, Lian, Tianquan, Bergman, Robert G, Harris, Charles B
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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