Understanding the Relationship between Surface Coverage and Molecular Orientation in Polar Self-Assembled Monolayers

We report here a study of surface coverage and molecular orientation in polar self-assembled monolayers (SAMs). The ordering in these SAMs arises from the competition of bonding to the surface and mutual steric effects that force alignment of the dipolar chromophores. The optimized molecular orienta...

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Veröffentlicht in:	Journal of the American Chemical Society 1996-03, Vol.118 (12), p.2950-2953
Hauptverfasser:	Buscher, C. Thomas, McBranch, Duncan, Li, DeQuan
Format:	Artikel
Sprache:	eng
Schlagworte:	40 CHEMISTRY HARMONIC GENERATION MOLECULAR STRUCTURE MOLECULES ORGANIC COMPOUNDS ORIENTATION PHYSICS POLAR COMPOUNDS SURFACES THIN FILMS TRANSMISSION ELECTRON MICROSCOPY
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