Synthesis, Resolution, and Determination of Absolute Configuration of a Vaulted 2,2‘-Binaphthol and a Vaulted 3,3‘-Biphenanthrol (VAPOL)

Two methods for the synthesis of vaulted biaryls were developed involving the reactions of carbene complexes with alkynes and the [2 + 2] cycloaddition of ketenes. The final step in the synthesis of 3,3‘-diphenyl-[2,2‘-binaphthalene]-1,1‘-diol (39) and 2,2‘-diphenyl-[3,3‘-biphenanthrene]-4,4‘-diol (...

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Veröffentlicht in:	Journal of the American Chemical Society 1996-04, Vol.118 (14), p.3392-3405
Hauptverfasser:	Bao, Jianming, Wulff, William D, Dominy, James B, Fumo, Michael J, Grant, Eugene B, Rob, Alexander C, Whitcomb, Mark C, Yeung, Siu-Man, Ostrander, Robert L, Rheingold, Arnold L
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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