Reductive Reactivity of the Organolanthanide Hydrides, [(C5Me5)2LnH] x , Leads to ansa-Allyl Cyclopentadienyl (η5-C5Me4CH2−C5Me4CH2-η3)2- and Trianionic Cyclooctatetraenyl (C8H7)3- Ligands

The reductive reactivity of lanthanide hydride ligands in the [(C5Me5)2LnH] x complexes (Ln = Sm, La, Y) was examined to see if these hydride ligands would react like the actinide hydrides in [(C5Me5)2AnH2]2 (An = U, Th) and [(C5Me5)2UH]2. Each lanthanide hydride complex reduces PhSSPh to make [(C5M...

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Veröffentlicht in:	Journal of the American Chemical Society 2008-07, Vol.130 (26), p.8555-8563
Hauptverfasser:	Evans, William J, Schmiege, Benjamin M, Lorenz, Sara E, Miller, Kevin A, Champagne, Timothy M, Ziller, Joseph W, DiPasquale, Antonio G, Rheingold, Arnold L
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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