Ring-Shaped Re(I) Multinuclear Complexes with Unique Photofunctional Properties
We synthesized for the first time a series of emissive ring-shaped Re(I) complexes (Re-rings) with various numbers of Re(I) units and various lengths of bridge ligands. The photophysical properties of the Re-rings could be varied widely through changes in the size of the central cavity. A smaller...
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| Veröffentlicht in: | Journal of the American Chemical Society 2013-09, Vol.135 (36), p.13266-13269 |
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| container_end_page | 13269 |
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| container_issue | 36 |
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| container_title | Journal of the American Chemical Society |
| container_volume | 135 |
| creator | Morimoto, Tatsuki Nishiura, Chiaki Tanaka, Marina Rohacova, Jana Nakagawa, Yuki Funada, Yusuke Koike, Kazuhide Yamamoto, Youhei Shishido, Sayaka Kojima, Tatsuhiro Saeki, Takuro Ozeki, Tomoji Ishitani, Osamu |
| description | We synthesized for the first time a series of emissive ring-shaped Re(I) complexes (Re-rings) with various numbers of Re(I) units and various lengths of bridge ligands. The photophysical properties of the Re-rings could be varied widely through changes in the size of the central cavity. A smaller central cavity of the Re-rings induced intramolecular π–π interactions between the ligands and consequently caused a stronger emission and a longer lifetime of the excited state. The Re-rings can function as efficient and durable photosensitizers. The combination of a trinuclear Re-ring photosensitizer with fac-[Re(bpy)(CO)3(MeCN)]+ (bpy = 2,2′-bipyridine) as a catalyst photocatalyzed CO2 reduction with the highest quantum yield of 82%. |
| doi_str_mv | 10.1021/ja406144h |
| format | Article |
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The photophysical properties of the Re-rings could be varied widely through changes in the size of the central cavity. A smaller central cavity of the Re-rings induced intramolecular π–π interactions between the ligands and consequently caused a stronger emission and a longer lifetime of the excited state. The Re-rings can function as efficient and durable photosensitizers. The combination of a trinuclear Re-ring photosensitizer with fac-[Re(bpy)(CO)3(MeCN)]+ (bpy = 2,2′-bipyridine) as a catalyst photocatalyzed CO2 reduction with the highest quantum yield of 82%.</description><identifier>ISSN: 0002-7863</identifier><identifier>EISSN: 1520-5126</identifier><identifier>DOI: 10.1021/ja406144h</identifier><identifier>PMID: 23968314</identifier><language>eng</language><publisher>United States: American Chemical Society</publisher><subject>Carbon Dioxide - chemistry ; Carbon Monoxide - chemical synthesis ; Carbon Monoxide - chemistry ; Catalysis ; Molecular Conformation ; Organometallic Compounds - chemical synthesis ; Organometallic Compounds - chemistry ; Oxidation-Reduction ; Photochemical Processes ; Photosensitizing Agents - chemical synthesis ; Photosensitizing Agents - chemistry ; Rhenium - chemistry ; Ultraviolet Rays</subject><ispartof>Journal of the American Chemical Society, 2013-09, Vol.135 (36), p.13266-13269</ispartof><rights>Copyright © 2013 American Chemical Society</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a361t-428639ee75789efaa028382d39562bd1a10b261d2ee17ae22d0d8ee9e4f517d03</citedby><cites>FETCH-LOGICAL-a361t-428639ee75789efaa028382d39562bd1a10b261d2ee17ae22d0d8ee9e4f517d03</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/ja406144h$$EPDF$$P50$$Gacs$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/ja406144h$$EHTML$$P50$$Gacs$$Hfree_for_read</linktohtml><link.rule.ids>314,776,780,2752,27055,27903,27904,56716,56766</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/23968314$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Morimoto, Tatsuki</creatorcontrib><creatorcontrib>Nishiura, Chiaki</creatorcontrib><creatorcontrib>Tanaka, Marina</creatorcontrib><creatorcontrib>Rohacova, Jana</creatorcontrib><creatorcontrib>Nakagawa, Yuki</creatorcontrib><creatorcontrib>Funada, Yusuke</creatorcontrib><creatorcontrib>Koike, Kazuhide</creatorcontrib><creatorcontrib>Yamamoto, Youhei</creatorcontrib><creatorcontrib>Shishido, Sayaka</creatorcontrib><creatorcontrib>Kojima, Tatsuhiro</creatorcontrib><creatorcontrib>Saeki, Takuro</creatorcontrib><creatorcontrib>Ozeki, Tomoji</creatorcontrib><creatorcontrib>Ishitani, Osamu</creatorcontrib><title>Ring-Shaped Re(I) Multinuclear Complexes with Unique Photofunctional Properties</title><title>Journal of the American Chemical Society</title><addtitle>J. Am. Chem. Soc</addtitle><description>We synthesized for the first time a series of emissive ring-shaped Re(I) complexes (Re-rings) with various numbers of Re(I) units and various lengths of bridge ligands. The photophysical properties of the Re-rings could be varied widely through changes in the size of the central cavity. A smaller central cavity of the Re-rings induced intramolecular π–π interactions between the ligands and consequently caused a stronger emission and a longer lifetime of the excited state. The Re-rings can function as efficient and durable photosensitizers. The combination of a trinuclear Re-ring photosensitizer with fac-[Re(bpy)(CO)3(MeCN)]+ (bpy = 2,2′-bipyridine) as a catalyst photocatalyzed CO2 reduction with the highest quantum yield of 82%.</description><subject>Carbon Dioxide - chemistry</subject><subject>Carbon Monoxide - chemical synthesis</subject><subject>Carbon Monoxide - chemistry</subject><subject>Catalysis</subject><subject>Molecular Conformation</subject><subject>Organometallic Compounds - chemical synthesis</subject><subject>Organometallic Compounds - chemistry</subject><subject>Oxidation-Reduction</subject><subject>Photochemical Processes</subject><subject>Photosensitizing Agents - chemical synthesis</subject><subject>Photosensitizing Agents - chemistry</subject><subject>Rhenium - chemistry</subject><subject>Ultraviolet Rays</subject><issn>0002-7863</issn><issn>1520-5126</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2013</creationdate><recordtype>article</recordtype><sourceid>N~.</sourceid><sourceid>EIF</sourceid><recordid>eNptkFFLwzAUhYMobk4f_APSF8E9VHOTNk0fZUwdTDamey5Zc2szuqYmLeq_tzLdk0-XAx-Hcz9CLoHeAmVwt1URFRBF5REZQsxoGAMTx2RIKWVhIgUfkDPvt32MmIRTMmA8FZJDNCSLlanfwpdSNaiDFd7MxsFzV7Wm7vIKlQsmdtdU-Ik--DBtGaxr895hsCxta4uuzltja1UFS2cbdK1Bf05OClV5vPi9I7J-mL5OnsL54nE2uZ-Higtow36H4CliEicyxUIpyiSXTPM0FmyjQQHdMAGaIUKikDFNtURMMSpiSDTlIzLe9-bOeu-wyBpndsp9ZUCzHynZQUrPXu3ZptvsUB_IPws9cL0HVO6zre1c_5P_p-gba1xoWA</recordid><startdate>20130911</startdate><enddate>20130911</enddate><creator>Morimoto, Tatsuki</creator><creator>Nishiura, Chiaki</creator><creator>Tanaka, Marina</creator><creator>Rohacova, Jana</creator><creator>Nakagawa, Yuki</creator><creator>Funada, Yusuke</creator><creator>Koike, Kazuhide</creator><creator>Yamamoto, Youhei</creator><creator>Shishido, Sayaka</creator><creator>Kojima, Tatsuhiro</creator><creator>Saeki, Takuro</creator><creator>Ozeki, Tomoji</creator><creator>Ishitani, Osamu</creator><general>American Chemical Society</general><scope>N~.</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20130911</creationdate><title>Ring-Shaped Re(I) Multinuclear Complexes with Unique Photofunctional Properties</title><author>Morimoto, Tatsuki ; Nishiura, Chiaki ; Tanaka, Marina ; Rohacova, Jana ; Nakagawa, Yuki ; Funada, Yusuke ; Koike, Kazuhide ; Yamamoto, Youhei ; Shishido, Sayaka ; Kojima, Tatsuhiro ; Saeki, Takuro ; Ozeki, Tomoji ; Ishitani, Osamu</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a361t-428639ee75789efaa028382d39562bd1a10b261d2ee17ae22d0d8ee9e4f517d03</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2013</creationdate><topic>Carbon Dioxide - chemistry</topic><topic>Carbon Monoxide - chemical synthesis</topic><topic>Carbon Monoxide - chemistry</topic><topic>Catalysis</topic><topic>Molecular Conformation</topic><topic>Organometallic Compounds - chemical synthesis</topic><topic>Organometallic Compounds - chemistry</topic><topic>Oxidation-Reduction</topic><topic>Photochemical Processes</topic><topic>Photosensitizing Agents - chemical synthesis</topic><topic>Photosensitizing Agents - chemistry</topic><topic>Rhenium - chemistry</topic><topic>Ultraviolet Rays</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Morimoto, Tatsuki</creatorcontrib><creatorcontrib>Nishiura, Chiaki</creatorcontrib><creatorcontrib>Tanaka, Marina</creatorcontrib><creatorcontrib>Rohacova, Jana</creatorcontrib><creatorcontrib>Nakagawa, Yuki</creatorcontrib><creatorcontrib>Funada, Yusuke</creatorcontrib><creatorcontrib>Koike, Kazuhide</creatorcontrib><creatorcontrib>Yamamoto, Youhei</creatorcontrib><creatorcontrib>Shishido, Sayaka</creatorcontrib><creatorcontrib>Kojima, Tatsuhiro</creatorcontrib><creatorcontrib>Saeki, Takuro</creatorcontrib><creatorcontrib>Ozeki, Tomoji</creatorcontrib><creatorcontrib>Ishitani, Osamu</creatorcontrib><collection>American Chemical Society (ACS) Open Access</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><jtitle>Journal of the American Chemical Society</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Morimoto, Tatsuki</au><au>Nishiura, Chiaki</au><au>Tanaka, Marina</au><au>Rohacova, Jana</au><au>Nakagawa, Yuki</au><au>Funada, Yusuke</au><au>Koike, Kazuhide</au><au>Yamamoto, Youhei</au><au>Shishido, Sayaka</au><au>Kojima, Tatsuhiro</au><au>Saeki, Takuro</au><au>Ozeki, Tomoji</au><au>Ishitani, Osamu</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Ring-Shaped Re(I) Multinuclear Complexes with Unique Photofunctional Properties</atitle><jtitle>Journal of the American Chemical Society</jtitle><addtitle>J. Am. Chem. Soc</addtitle><date>2013-09-11</date><risdate>2013</risdate><volume>135</volume><issue>36</issue><spage>13266</spage><epage>13269</epage><pages>13266-13269</pages><issn>0002-7863</issn><eissn>1520-5126</eissn><abstract>We synthesized for the first time a series of emissive ring-shaped Re(I) complexes (Re-rings) with various numbers of Re(I) units and various lengths of bridge ligands. The photophysical properties of the Re-rings could be varied widely through changes in the size of the central cavity. A smaller central cavity of the Re-rings induced intramolecular π–π interactions between the ligands and consequently caused a stronger emission and a longer lifetime of the excited state. The Re-rings can function as efficient and durable photosensitizers. The combination of a trinuclear Re-ring photosensitizer with fac-[Re(bpy)(CO)3(MeCN)]+ (bpy = 2,2′-bipyridine) as a catalyst photocatalyzed CO2 reduction with the highest quantum yield of 82%.</abstract><cop>United States</cop><pub>American Chemical Society</pub><pmid>23968314</pmid><doi>10.1021/ja406144h</doi><tpages>4</tpages><oa>free_for_read</oa></addata></record> |
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| source | ACS Publications; MEDLINE |
| subjects | Carbon Dioxide - chemistry Carbon Monoxide - chemical synthesis Carbon Monoxide - chemistry Catalysis Molecular Conformation Organometallic Compounds - chemical synthesis Organometallic Compounds - chemistry Oxidation-Reduction Photochemical Processes Photosensitizing Agents - chemical synthesis Photosensitizing Agents - chemistry Rhenium - chemistry Ultraviolet Rays |
| title | Ring-Shaped Re(I) Multinuclear Complexes with Unique Photofunctional Properties |
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