[[(Me3Si)2CH]2 i PrSi(NHC)SiSi(Me)Si i Pr[CH(SiMe3)2]2]+: A Molecule with Disilenyl Cation Character

Reaction of the disilyne–NHC complex 1 [RLSiSiR: (R = Si i Pr[CH(SiMe3)2]2, L = NHC)] with MeOTf gave the cation 2 [RLSiSiRMe]+, which is the first example of a base-stabilized heavy group 14 element analogue with vinyl cation character. Cation 2 has been fully characterized by multinuclear NMR sp...

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Veröffentlicht in:	Journal of the American Chemical Society 2012-01, Vol.134 (2), p.886-889
Hauptverfasser:	Yamaguchi, Torahiko, Asay, Matthew, Sekiguchi, Akira
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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