Calix[4]pyrrole as a Chloride Anion Receptor: Solvent and Countercation Effects

The interaction of calixpyrrole with several chloride salts has been studied in the solid state by X-ray crystallography as well as in solution by isothermal titration calorimetry (ITC) and 1H NMR spectroscopic titrations. The titration results in dimethylsulfoxide, acetonitrile, nitromethane, 1,2-d...

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Veröffentlicht in:	Journal of the American Chemical Society 2006-09, Vol.128 (37), p.12281-12288
Hauptverfasser:	Sessler, Jonathan L, Gross, Dustin E, Cho, Won-Seob, Lynch, Vincent M, Schmidtchen, Franz P, Bates, Gareth W, Light, Mark E, Gale, Philip A
Format:	Artikel
Sprache:	eng
Schlagworte:	Alicyclic compounds Alicyclic compounds, terpenoids, prostaglandins, steroids Anions Calixarenes - chemistry Calixarenes - metabolism Calorimetry Chemistry Chlorides - chemistry Chlorides - metabolism Crystallography, X-Ray Exact sciences and technology General and physical chemistry Heterocyclic compounds Heterocyclic compounds with several n hetero atoms in the same ring, in separated rings or in fused rings Kinetics Models, Molecular Molecular Structure Organic chemistry Porphyrins - chemistry Porphyrins - metabolism Preparations and properties Quaternary Ammonium Compounds - chemistry Quaternary Ammonium Compounds - metabolism Solutions Titrimetry
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