Matrix Photochemistry of s yn-(Chlorocarbonyl)sulfenyl Bromide, s yn-ClC(O)SBr:  Precursor to the Novel Species a nti-ClC(O)SBr, s yn-BrC(O)SCl, and BrSCl

The vapor of (chlorocarbonyl)sulfenyl bromide, ClC(O)SBr, was isolated in solid Ar, Kr, N2, and Ar doped with 5% CO at 15 K, and the matrix was subsequently irradiated with broad-band UV−visible light (200 ≤ λ ≤ 800 nm), the changes being followed by reference to the IR spectrum of the matrix. The i...

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Veröffentlicht in:	Journal of the American Chemical Society 2001-06, Vol.123 (24), p.5794-5801
Hauptverfasser:	Romano, Rosana M, Della Védova, Carlos O, Downs, Anthony J, Greene, Tim M
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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