Role of hyperconjugation in secondary .beta.-deuterium isotope effects

The effect of hyperconjugation of the magnitudes of secondary BETA-deuterium isotope effects has been investigated by ion cyclotron resonance spectroscopy and a b initio molecular orbital theory. Isotope effects measured for ion-molecule equilibria involving formation either of a nonbonded pair of e...

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Veröffentlicht in:	J. Am. Chem. Soc.; (United States) 1979-09, Vol.101 (19), p.5532-5536
Hauptverfasser:	DeFrees, D. J, Taagepera, M, Levi, B. A, Pollack, S. K, Summerhays, K. D, Taft, R. W, Wolfsberg, M, Hehre, W. J
Format:	Artikel
Sprache:	eng
Schlagworte:	400202 - Isotope Effects, Isotope Exchange, & Isotope Separation ALKYL RADICALS BETA PARTICLES CHARGED PARTICLES DEUTERIUM ELECTRONS ELEMENTARY PARTICLES FERMIONS HYDROGEN ISOTOPES INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY ION CYCLOTRON RESONANCE SPECTROSCOPY ION SPECTROSCOPY ISOTOPE EFFECTS ISOTOPES LEPTONS LIGHT NUCLEI METHYL RADICALS MOLECULAR ORBITAL METHOD NUCLEI ODD-ODD NUCLEI RADICALS SPECTROSCOPY STABLE ISOTOPES
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