Syntheses and electronic structures of decamethylmanganocenes
The syntheses of ((C/sub 5/(CH/sub 3/)/sub 5/)/sub 2/Mn)PF/sub 6/, (C/sub 5/(CH/sub 3/)/sub 5/)/sub 2/Mn, and Na((C/sub 5/(CH/sub 3/)/sub 5/)/sub 2/Mn) are described. Magnetic susceptibility, infrared, electrochemical, NMR, and reactivity studies suggest the formulation of these complexes as low-spi...
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| Veröffentlicht in: | J. Am. Chem. Soc.; (United States) 1979-07, Vol.101 (14), p.3853-3857 |
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| container_title | J. Am. Chem. Soc.; (United States) |
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| creator | Robbins, John L Edelstein, Norman M Cooper, Stephen R Smart, James C |
| description | The syntheses of ((C/sub 5/(CH/sub 3/)/sub 5/)/sub 2/Mn)PF/sub 6/, (C/sub 5/(CH/sub 3/)/sub 5/)/sub 2/Mn, and Na((C/sub 5/(CH/sub 3/)/sub 5/)/sub 2/Mn) are described. Magnetic susceptibility, infrared, electrochemical, NMR, and reactivity studies suggest the formulation of these complexes as low-spin 16-, 17-, and 18-electron planar metallocenes. EPR spectra of the neutral complex are consistent with the /sup 2/E/sub 2g/ configuration determined for other low-spin 17-electron metallocenes. 1 figure, 3 tables. |
| doi_str_mv | 10.1021/ja00508a023 |
| format | Article |
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Magnetic susceptibility, infrared, electrochemical, NMR, and reactivity studies suggest the formulation of these complexes as low-spin 16-, 17-, and 18-electron planar metallocenes. EPR spectra of the neutral complex are consistent with the /sup 2/E/sub 2g/ configuration determined for other low-spin 17-electron metallocenes. 1 figure, 3 tables.</description><identifier>ISSN: 0002-7863</identifier><identifier>EISSN: 1520-5126</identifier><identifier>DOI: 10.1021/ja00508a023</identifier><language>eng</language><publisher>United States: American Chemical Society</publisher><subject>400104 - Spectral Procedures- (-1987) ; 400201 - Chemical & Physicochemical Properties ; 400301 - Organic Chemistry- Chemical & Physicochemical Properties- (-1987) ; CHEMISTRY ; COMPLEXES ; ELECTROCHEMISTRY ; ELECTRONIC STRUCTURE ; INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY ; MAGNETIC PROPERTIES ; MAGNETIC RESONANCE ; MAGNETIC SUSCEPTIBILITY ; MANGANESE COMPLEXES ; NUCLEAR MAGNETIC RESONANCE ; PHYSICAL PROPERTIES ; RESONANCE ; SYNTHESIS ; TRANSITION ELEMENT COMPLEXES</subject><ispartof>J. Am. Chem. 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Am. Chem. Soc.; (United States)</title><addtitle>J. Am. Chem. Soc</addtitle><description>The syntheses of ((C/sub 5/(CH/sub 3/)/sub 5/)/sub 2/Mn)PF/sub 6/, (C/sub 5/(CH/sub 3/)/sub 5/)/sub 2/Mn, and Na((C/sub 5/(CH/sub 3/)/sub 5/)/sub 2/Mn) are described. Magnetic susceptibility, infrared, electrochemical, NMR, and reactivity studies suggest the formulation of these complexes as low-spin 16-, 17-, and 18-electron planar metallocenes. EPR spectra of the neutral complex are consistent with the /sup 2/E/sub 2g/ configuration determined for other low-spin 17-electron metallocenes. 1 figure, 3 tables.</description><subject>400104 - Spectral Procedures- (-1987)</subject><subject>400201 - Chemical & Physicochemical Properties</subject><subject>400301 - Organic Chemistry- Chemical & Physicochemical Properties- (-1987)</subject><subject>CHEMISTRY</subject><subject>COMPLEXES</subject><subject>ELECTROCHEMISTRY</subject><subject>ELECTRONIC STRUCTURE</subject><subject>INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY</subject><subject>MAGNETIC PROPERTIES</subject><subject>MAGNETIC RESONANCE</subject><subject>MAGNETIC SUSCEPTIBILITY</subject><subject>MANGANESE COMPLEXES</subject><subject>NUCLEAR MAGNETIC RESONANCE</subject><subject>PHYSICAL PROPERTIES</subject><subject>RESONANCE</subject><subject>SYNTHESIS</subject><subject>TRANSITION ELEMENT COMPLEXES</subject><issn>0002-7863</issn><issn>1520-5126</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1979</creationdate><recordtype>article</recordtype><recordid>eNpt0EtLAzEQAOAgCtbqyT-wePEgq7N57h48SPFdVGzFY0hns3Zrm5UkBfvvjayIB0_DMB_zIuSwgNMCaHG2MAACSgOUbZFBISjkoqBymwwAgOaqlGyX7IWwSCmnZTEg55ONi3MbbMiMqzO7tBh951rMQvRrjGufKl2T1RbNysb5Zrky7s24Dq2zYZ_sNGYZ7MFPHJKXq8vp6CYfP17fji7GuWFSxLw2JaiaccNQlQ2IulKN4RK5QmDIZ4pxXiqLtZUCoOFKVGXDFK1naSrwig3JUd-3C7HVAdtocY6dc2lbLZRklPOETnqEvgvB20Z_-HZl_EYXoL_fo_-8J-m8122I9vOXGv-upWJK6OnTRNPxQ_Us7u_0a_LHvTcY9KJbe5cO_rfzF0FCc2U</recordid><startdate>19790701</startdate><enddate>19790701</enddate><creator>Robbins, John L</creator><creator>Edelstein, Norman M</creator><creator>Cooper, Stephen R</creator><creator>Smart, James C</creator><general>American Chemical Society</general><scope>BSCLL</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>OTOTI</scope></search><sort><creationdate>19790701</creationdate><title>Syntheses and electronic structures of decamethylmanganocenes</title><author>Robbins, John L ; Edelstein, Norman M ; Cooper, Stephen R ; Smart, James C</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a365t-da807d34a3c78f05d97fa46c47c03c4b734487ecde6500f47598f372dbeca0493</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1979</creationdate><topic>400104 - Spectral Procedures- (-1987)</topic><topic>400201 - Chemical & Physicochemical Properties</topic><topic>400301 - Organic Chemistry- Chemical & Physicochemical Properties- (-1987)</topic><topic>CHEMISTRY</topic><topic>COMPLEXES</topic><topic>ELECTROCHEMISTRY</topic><topic>ELECTRONIC STRUCTURE</topic><topic>INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY</topic><topic>MAGNETIC PROPERTIES</topic><topic>MAGNETIC RESONANCE</topic><topic>MAGNETIC SUSCEPTIBILITY</topic><topic>MANGANESE COMPLEXES</topic><topic>NUCLEAR MAGNETIC RESONANCE</topic><topic>PHYSICAL PROPERTIES</topic><topic>RESONANCE</topic><topic>SYNTHESIS</topic><topic>TRANSITION ELEMENT COMPLEXES</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Robbins, John L</creatorcontrib><creatorcontrib>Edelstein, Norman M</creatorcontrib><creatorcontrib>Cooper, Stephen R</creatorcontrib><creatorcontrib>Smart, James C</creatorcontrib><creatorcontrib>Univ. of California, Berkeley</creatorcontrib><collection>Istex</collection><collection>CrossRef</collection><collection>OSTI.GOV</collection><jtitle>J. Am. Chem. Soc.; (United States)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Robbins, John L</au><au>Edelstein, Norman M</au><au>Cooper, Stephen R</au><au>Smart, James C</au><aucorp>Univ. of California, Berkeley</aucorp><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Syntheses and electronic structures of decamethylmanganocenes</atitle><jtitle>J. Am. Chem. Soc.; (United States)</jtitle><addtitle>J. Am. Chem. Soc</addtitle><date>1979-07-01</date><risdate>1979</risdate><volume>101</volume><issue>14</issue><spage>3853</spage><epage>3857</epage><pages>3853-3857</pages><issn>0002-7863</issn><eissn>1520-5126</eissn><abstract>The syntheses of ((C/sub 5/(CH/sub 3/)/sub 5/)/sub 2/Mn)PF/sub 6/, (C/sub 5/(CH/sub 3/)/sub 5/)/sub 2/Mn, and Na((C/sub 5/(CH/sub 3/)/sub 5/)/sub 2/Mn) are described. Magnetic susceptibility, infrared, electrochemical, NMR, and reactivity studies suggest the formulation of these complexes as low-spin 16-, 17-, and 18-electron planar metallocenes. EPR spectra of the neutral complex are consistent with the /sup 2/E/sub 2g/ configuration determined for other low-spin 17-electron metallocenes. 1 figure, 3 tables.</abstract><cop>United States</cop><pub>American Chemical Society</pub><doi>10.1021/ja00508a023</doi><tpages>5</tpages><oa>free_for_read</oa></addata></record> |
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| source | ACS Publications |
| subjects | 400104 - Spectral Procedures- (-1987) 400201 - Chemical & Physicochemical Properties 400301 - Organic Chemistry- Chemical & Physicochemical Properties- (-1987) CHEMISTRY COMPLEXES ELECTROCHEMISTRY ELECTRONIC STRUCTURE INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY MAGNETIC PROPERTIES MAGNETIC RESONANCE MAGNETIC SUSCEPTIBILITY MANGANESE COMPLEXES NUCLEAR MAGNETIC RESONANCE PHYSICAL PROPERTIES RESONANCE SYNTHESIS TRANSITION ELEMENT COMPLEXES |
| title | Syntheses and electronic structures of decamethylmanganocenes |
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