The use of chlorine kinetic isotope effects for evaluating ion pairing in nucleophilic displacements at saturated carbon

Use of the Winstein scheme to describe ion pairing leads to the conclusion that chlorine kinetic isotope effects (KIE) are primarily responsive to processes involving the covalently bound chlorine and less indicative of reactions which occur after the formation of the initial ion pair. This conclusi...

Ausführliche Beschreibung