Oxygen-17 magnetic resonance study of oxygen exchange between arsenite ion and solvent water

Oxygen-17 magnetic resonance spectra of aqueous solutions of sodium arsenite were measured for 0.6 < (As(III)) < 4.1 m, 10 < t < 90/sup 0/C. Line broadening of the water resonance in the 40 to 90/sup 0/C range gives the rate of oxygen exchange between AsO(OH)/sub 2//sup -/ and solvent wa...

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Veröffentlicht in:	J. Am. Chem. Soc.; (United States) 1978-06, Vol.100 (12), p.3776-3780
Hauptverfasser:	Copenhafer, William C, Rieger, Philip H
Format:	Artikel
Sprache:	eng
Schlagworte:	ANIONS AQUEOUS SOLUTIONS ARSENIC COMPOUNDS CHARGED PARTICLES CHEMICAL REACTION KINETICS DISPERSIONS EVEN-ODD NUCLEI HYDROGEN COMPOUNDS INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY IONS ISOTOPES KINETICS LIGHT NUCLEI MAGNETIC RESONANCE MIXTURES NUCLEAR MAGNETIC RESONANCE NUCLEI OXYGEN 17 OXYGEN COMPOUNDS OXYGEN ISOTOPES REACTION KINETICS RESONANCE SOLUTIONS STABLE ISOTOPES 400201 > Chemical & Physicochemical Properties WATER
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