Catalysis of carbon monoxide hydrogenation by soluble mononuclear complexes

The homogeneous hydrogenation of CO to CH/sub 3/OH, higher primary alcohols and their formate esters in the presence of Co/sub 2/(CO)/sub 8/ using benzene, heptane, and p-dioxane as solvents is reported. The principal rate-determining step is first order in the soluble mononuclear species, HCo(CO)/s...

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Veröffentlicht in:	J. Am. Chem. Soc.; (United States) 1978-05, Vol.100 (11), p.3623-3625
Hauptverfasser:	Rathke, J. W, Feder, H. M
Format:	Artikel
Sprache:	eng
Schlagworte:	10 SYNTHETIC FUELS 400301 > Organic Chemistry-- Chemical & Physicochemical Properties-- (-1987) ALCOHOLS ALKANES AROMATICS BENZENE CARBON COMPOUNDS CARBON MONOXIDE CARBON OXIDES CARBOXYLIC ACID SALTS CATALYSTS CATALYTIC EFFECTS CHALCOGENIDES CHEMICAL REACTION KINETICS CHEMICAL REACTION YIELD CHEMICAL REACTIONS COBALT CRYOGENIC FLUIDS DIOXANE ELEMENTS ENTHALPY ETHANOL FLUIDS FORMATES GASES HEPTANE HETEROCYCLIC COMPOUNDS HYDROCARBONS HYDROGEN HYDROXY COMPOUNDS INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY KINETICS METALS METHANATION METHANOL NONMETALS ORGANIC COMPOUNDS ORGANIC OXYGEN COMPOUNDS OXIDES OXYGEN COMPOUNDS PHYSICAL PROPERTIES PROPANOLS REACTION KINETICS SYNTHESIS GAS THERMODYNAMIC PROPERTIES TRANSITION ELEMENTS YIELDS 090221 > Alcohol Fuels-- Chemical Synthesis-- (1976-1989)
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