Reaction of singlet oxygen with 4-methyl-2,3-dihydro-.gamma.-pyrans

4-methyl-1,3-dihydro-..gamma..-pyran (1) reacts with singlet molecular oxygen to yield both a dioxetane 2 and an allylic hydroperoxide 3, each of which is converted by heat into a single product stable under conditions of vapor chromatography. The product composition from 1 and from 1-4-d has been d...

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Veröffentlicht in:	J. Am. Chem. Soc.; (United States) 1977-11, Vol.99 (24), p.7977-7986
Hauptverfasser:	Frimer, Aryeh A, Bartlett, Paul D, Boschung, Andre F, Jewett, John G
Format:	Artikel
Sprache:	eng
Schlagworte:	400302 - Organic Chemistry- Isotope Effects- (-1987) BETA DECAY RADIOISOTOPES BETA-MINUS DECAY RADIOISOTOPES CHEMICAL REACTION KINETICS CRYOGENIC FLUIDS DEUTERIUM ELEMENTS FLUIDS HETEROCYCLIC COMPOUNDS HYDROGEN ISOTOPES INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY ISOTOPE EFFECTS ISOTOPES KINETICS LIGHT NUCLEI NONMETALS NUCLEI ODD-EVEN NUCLEI ODD-ODD NUCLEI ORGANIC COMPOUNDS ORGANIC OXYGEN COMPOUNDS OXYGEN PYRANS RADIOISOTOPES REACTION KINETICS STABLE ISOTOPES TRITIUM YEARS LIVING RADIOISOTOPES
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