Energetics of the rearrangement of neutral and ionized perfluorocyclopropane to perfluoropropylene. Use of infrared multiphoton dissociation spectra to identify structural isomers of molecular ions

Infrared photodissociation spectroscopy is used to compare the structure of gas-phase C/sub 3/F/sub 6//sup +/ ions obtained by electron-impact ionization of two isomeric precursors: perfluoropropylene and perfluorocyclopropane. Photodissociation spectra are obtained by observing the extent of multip...

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Bibliographische Detailangaben
Veröffentlicht in:	J. Am. Chem. Soc.; (United States) 1981-07, Vol.103 (14), p.3967-3971
Hauptverfasser:	Bomse, D. S, Berman, D. Wayne, Beauchamp, J. L
Format:	Artikel
Sprache:	eng
Schlagworte:	400301 - Organic Chemistry- Chemical & Physicochemical Properties- (-1987) ALKANES CARBON DIOXIDE LASERS CHEMICAL REACTIONS CHEMISTRY CYCLOALKANES DATA DISSOCIATION ELECTROMAGNETIC RADIATION ENTHALPY EXPERIMENTAL DATA FLUORINATED ALIPHATIC HYDROCARBONS FORMATION HEAT GAS LASERS HALOGENATED ALIPHATIC HYDROCARBONS HYDROCARBONS INFORMATION INFRARED SPECTRA INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY ION CYCLOTRON RESONANCE SPECTROSCOPY ION SPECTROSCOPY ISOMERIZATION LASER RADIATION LASERS NUMERICAL DATA ORGANIC COMPOUNDS ORGANIC FLUORINE COMPOUNDS ORGANIC HALOGEN COMPOUNDS PHOTOCHEMISTRY PHYSICAL PROPERTIES RADIATIONS REACTION HEAT SPECTRA SPECTROSCOPY THERMODYNAMIC PROPERTIES
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