Partial oxidation of methane by nitrous oxide over molybdenum on silica
Kinetic data are presented for the partial oxidation of methane to methanol and formaldehyde by nitrous oxide catalysed by molybdenum supported on silica when steam is present in the system. The data are used as evidence to show how the selective oxidation mechanism fits into an overall reaction sch...
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| Veröffentlicht in: | J. Am. Chem. Soc.; (United States) 1984-07, Vol.106 (15), p.4117-4121 |
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| container_end_page | 4121 |
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| container_issue | 15 |
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| container_title | J. Am. Chem. Soc.; (United States) |
| container_volume | 106 |
| creator | Liu, H. F Liu, R. S Liew, K. Y Johnson, R. E Lunsford, J. H |
| description | Kinetic data are presented for the partial oxidation of methane to methanol and formaldehyde by nitrous oxide catalysed by molybdenum supported on silica when steam is present in the system. The data are used as evidence to show how the selective oxidation mechanism fits into an overall reaction scheme. Moreover, in support of this selective mechanism, spectroscopic evidence is given for the formation of methyl radicals and methoxide ions on the surface. 12 references, 7 figures, 1 table. |
| doi_str_mv | 10.1021/ja00327a009 |
| format | Article |
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F ; Liu, R. S ; Liew, K. Y ; Johnson, R. E ; Lunsford, J. H</creator><creatorcontrib>Liu, H. F ; Liu, R. S ; Liew, K. Y ; Johnson, R. E ; Lunsford, J. H ; Texas A and M Univ., College Station</creatorcontrib><description>Kinetic data are presented for the partial oxidation of methane to methanol and formaldehyde by nitrous oxide catalysed by molybdenum supported on silica when steam is present in the system. The data are used as evidence to show how the selective oxidation mechanism fits into an overall reaction scheme. Moreover, in support of this selective mechanism, spectroscopic evidence is given for the formation of methyl radicals and methoxide ions on the surface. 12 references, 7 figures, 1 table.</description><identifier>ISSN: 0002-7863</identifier><identifier>EISSN: 1520-5126</identifier><identifier>DOI: 10.1021/ja00327a009</identifier><identifier>CODEN: JACSAT</identifier><language>eng</language><publisher>Washington, DC: American Chemical Society</publisher><subject>400301 - Organic Chemistry- Chemical & Physicochemical Properties- (-1987) ; ALKANES ; CATALYSIS ; CATALYTIC EFFECTS ; CHALCOGENIDES ; CHEMICAL REACTION KINETICS ; CHEMICAL REACTIONS ; Chemistry ; DATA ; ELECTRON SPIN RESONANCE ; ELEMENTS ; Exact sciences and technology ; EXPERIMENTAL DATA ; HETEROGENEOUS CATALYSIS ; HYDROCARBONS ; INFORMATION ; INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY ; KINETICS ; Kinetics and mechanisms ; MAGNETIC RESONANCE ; METALS ; METHANE ; MOLYBDENUM ; NITROGEN COMPOUNDS ; NITROGEN OXIDES ; NITROUS OXIDE ; NUMERICAL DATA ; Organic chemistry ; ORGANIC COMPOUNDS ; OXIDATION ; OXIDES ; OXYGEN COMPOUNDS ; RADICALS ; REACTION KINETICS ; Reactivity and mechanisms ; RESONANCE ; TRANSITION ELEMENTS</subject><ispartof>J. 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Soc.; (United States), 1984-07, Vol.106 (15), p.4117-4121</ispartof><rights>1984 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a423t-d5a19f8b1aae14e81fe613f64a5726ad7bd27389eba17d60455337672081fd263</citedby></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/ja00327a009$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/ja00327a009$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,776,780,881,2752,27055,27903,27904,56715,56765</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=9670377$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.osti.gov/biblio/6507683$$D View this record in Osti.gov$$Hfree_for_read</backlink></links><search><creatorcontrib>Liu, H. F</creatorcontrib><creatorcontrib>Liu, R. S</creatorcontrib><creatorcontrib>Liew, K. Y</creatorcontrib><creatorcontrib>Johnson, R. E</creatorcontrib><creatorcontrib>Lunsford, J. H</creatorcontrib><creatorcontrib>Texas A and M Univ., College Station</creatorcontrib><title>Partial oxidation of methane by nitrous oxide over molybdenum on silica</title><title>J. Am. Chem. Soc.; (United States)</title><addtitle>J. Am. Chem. Soc</addtitle><description>Kinetic data are presented for the partial oxidation of methane to methanol and formaldehyde by nitrous oxide catalysed by molybdenum supported on silica when steam is present in the system. The data are used as evidence to show how the selective oxidation mechanism fits into an overall reaction scheme. Moreover, in support of this selective mechanism, spectroscopic evidence is given for the formation of methyl radicals and methoxide ions on the surface. 12 references, 7 figures, 1 table.</description><subject>400301 - Organic Chemistry- Chemical & Physicochemical Properties- (-1987)</subject><subject>ALKANES</subject><subject>CATALYSIS</subject><subject>CATALYTIC EFFECTS</subject><subject>CHALCOGENIDES</subject><subject>CHEMICAL REACTION KINETICS</subject><subject>CHEMICAL REACTIONS</subject><subject>Chemistry</subject><subject>DATA</subject><subject>ELECTRON SPIN RESONANCE</subject><subject>ELEMENTS</subject><subject>Exact sciences and technology</subject><subject>EXPERIMENTAL DATA</subject><subject>HETEROGENEOUS CATALYSIS</subject><subject>HYDROCARBONS</subject><subject>INFORMATION</subject><subject>INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY</subject><subject>KINETICS</subject><subject>Kinetics and mechanisms</subject><subject>MAGNETIC RESONANCE</subject><subject>METALS</subject><subject>METHANE</subject><subject>MOLYBDENUM</subject><subject>NITROGEN COMPOUNDS</subject><subject>NITROGEN OXIDES</subject><subject>NITROUS OXIDE</subject><subject>NUMERICAL DATA</subject><subject>Organic chemistry</subject><subject>ORGANIC COMPOUNDS</subject><subject>OXIDATION</subject><subject>OXIDES</subject><subject>OXYGEN COMPOUNDS</subject><subject>RADICALS</subject><subject>REACTION KINETICS</subject><subject>Reactivity and mechanisms</subject><subject>RESONANCE</subject><subject>TRANSITION ELEMENTS</subject><issn>0002-7863</issn><issn>1520-5126</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1984</creationdate><recordtype>article</recordtype><recordid>eNpt0M9LwzAUB_AgCs7pyX-giOBBqvnRJu1Rhk5x6tB58RJe05Rlts1IMtn-ezsrw4OXPML7vMfji9ApwVcEU3K9AIwZFd2b76EBSSmOU0L5PhpgjGksMs4O0ZH3i-6b0IwM0HgKLhioI7s2JQRj28hWUaPDHFodFZuoNcHZlf_p68h-aRc1tt4UpW5XTdRxb2qj4BgdVFB7ffJbh-j97nY2uo8nL-OH0c0khoSyEJcpkLzKCgKgSaIzUmlOWMUTSAXlUIqipIJluS6AiJLjJE0ZE1xQ3NGScjZEZ_1e64ORXpmg1VzZttUqSJ5iwTPWocseKWe9d7qSS2cacBtJsNwGJf8E1enzXi_BK6grB60yfjeSc4GZEB2Le2Z80OtdG9yn5IKJVM6mb5J_PD2-Js-J3PqL3oPycmFXru1y-feAb646gmE</recordid><startdate>198407</startdate><enddate>198407</enddate><creator>Liu, H. F</creator><creator>Liu, R. S</creator><creator>Liew, K. Y</creator><creator>Johnson, R. E</creator><creator>Lunsford, J. H</creator><general>American Chemical Society</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>OTOTI</scope></search><sort><creationdate>198407</creationdate><title>Partial oxidation of methane by nitrous oxide over molybdenum on silica</title><author>Liu, H. F ; Liu, R. S ; Liew, K. Y ; Johnson, R. E ; Lunsford, J. H</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a423t-d5a19f8b1aae14e81fe613f64a5726ad7bd27389eba17d60455337672081fd263</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1984</creationdate><topic>400301 - Organic Chemistry- Chemical & Physicochemical Properties- (-1987)</topic><topic>ALKANES</topic><topic>CATALYSIS</topic><topic>CATALYTIC EFFECTS</topic><topic>CHALCOGENIDES</topic><topic>CHEMICAL REACTION KINETICS</topic><topic>CHEMICAL REACTIONS</topic><topic>Chemistry</topic><topic>DATA</topic><topic>ELECTRON SPIN RESONANCE</topic><topic>ELEMENTS</topic><topic>Exact sciences and technology</topic><topic>EXPERIMENTAL DATA</topic><topic>HETEROGENEOUS CATALYSIS</topic><topic>HYDROCARBONS</topic><topic>INFORMATION</topic><topic>INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY</topic><topic>KINETICS</topic><topic>Kinetics and mechanisms</topic><topic>MAGNETIC RESONANCE</topic><topic>METALS</topic><topic>METHANE</topic><topic>MOLYBDENUM</topic><topic>NITROGEN COMPOUNDS</topic><topic>NITROGEN OXIDES</topic><topic>NITROUS OXIDE</topic><topic>NUMERICAL DATA</topic><topic>Organic chemistry</topic><topic>ORGANIC COMPOUNDS</topic><topic>OXIDATION</topic><topic>OXIDES</topic><topic>OXYGEN COMPOUNDS</topic><topic>RADICALS</topic><topic>REACTION KINETICS</topic><topic>Reactivity and mechanisms</topic><topic>RESONANCE</topic><topic>TRANSITION ELEMENTS</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Liu, H. F</creatorcontrib><creatorcontrib>Liu, R. S</creatorcontrib><creatorcontrib>Liew, K. Y</creatorcontrib><creatorcontrib>Johnson, R. E</creatorcontrib><creatorcontrib>Lunsford, J. H</creatorcontrib><creatorcontrib>Texas A and M Univ., College Station</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>OSTI.GOV</collection><jtitle>J. Am. Chem. Soc.; (United States)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Liu, H. F</au><au>Liu, R. S</au><au>Liew, K. Y</au><au>Johnson, R. E</au><au>Lunsford, J. H</au><aucorp>Texas A and M Univ., College Station</aucorp><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Partial oxidation of methane by nitrous oxide over molybdenum on silica</atitle><jtitle>J. Am. Chem. Soc.; (United States)</jtitle><addtitle>J. Am. Chem. Soc</addtitle><date>1984-07</date><risdate>1984</risdate><volume>106</volume><issue>15</issue><spage>4117</spage><epage>4121</epage><pages>4117-4121</pages><issn>0002-7863</issn><eissn>1520-5126</eissn><coden>JACSAT</coden><abstract>Kinetic data are presented for the partial oxidation of methane to methanol and formaldehyde by nitrous oxide catalysed by molybdenum supported on silica when steam is present in the system. The data are used as evidence to show how the selective oxidation mechanism fits into an overall reaction scheme. Moreover, in support of this selective mechanism, spectroscopic evidence is given for the formation of methyl radicals and methoxide ions on the surface. 12 references, 7 figures, 1 table.</abstract><cop>Washington, DC</cop><pub>American Chemical Society</pub><doi>10.1021/ja00327a009</doi><tpages>5</tpages></addata></record> |
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| identifier | ISSN: 0002-7863 |
| ispartof | J. Am. Chem. Soc.; (United States), 1984-07, Vol.106 (15), p.4117-4121 |
| issn | 0002-7863 1520-5126 |
| language | eng |
| recordid | cdi_crossref_primary_10_1021_ja00327a009 |
| source | ACS Publications |
| subjects | 400301 - Organic Chemistry- Chemical & Physicochemical Properties- (-1987) ALKANES CATALYSIS CATALYTIC EFFECTS CHALCOGENIDES CHEMICAL REACTION KINETICS CHEMICAL REACTIONS Chemistry DATA ELECTRON SPIN RESONANCE ELEMENTS Exact sciences and technology EXPERIMENTAL DATA HETEROGENEOUS CATALYSIS HYDROCARBONS INFORMATION INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY KINETICS Kinetics and mechanisms MAGNETIC RESONANCE METALS METHANE MOLYBDENUM NITROGEN COMPOUNDS NITROGEN OXIDES NITROUS OXIDE NUMERICAL DATA Organic chemistry ORGANIC COMPOUNDS OXIDATION OXIDES OXYGEN COMPOUNDS RADICALS REACTION KINETICS Reactivity and mechanisms RESONANCE TRANSITION ELEMENTS |
| title | Partial oxidation of methane by nitrous oxide over molybdenum on silica |
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