Molecular organoosmium chemistry and catalysis on the basic magnesium oxide surface

The complex (H/sub 2/Os(CO)/sub 4/) is deprotonated upon adsorption on the basic surface of magnesia. The resulting (HOs(CO)/sub 4/)/sup -/ is held strongly to the surface by a localized carbonyl-Mg/sup 2 +/ interaction analogous to the contact anion ion pairing observed for (Na)(HOs(CO)/sub 4/) in...

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Veröffentlicht in:	J. Am. Chem. Soc.; (United States) 1986, Vol.108 (1), p.81-89
Hauptverfasser:	Lamb, H. Henry, Gates, Bruce C
Format:	Artikel
Sprache:	eng
Schlagworte:	400301 - Organic Chemistry- Chemical & Physicochemical Properties- (-1987) ADSORPTION ALKALINE EARTH METAL COMPOUNDS ANIONS Applied sciences CARBON COMPOUNDS CARBON MONOXIDE CARBON OXIDES CARBONYLS CATALYSIS CATALYSTS Catalysts: preparations and properties CATALYTIC EFFECTS Catalytic reactions CHALCOGENIDES CHARGED PARTICLES CHEMICAL REACTIONS Chemistry COMPLEXES DATA Exact sciences and technology EXPERIMENTAL DATA General and physical chemistry General. Nomenclature, chemical documentation, computer chemistry HIGH TEMPERATURE INFORMATION INFRARED SPECTRA INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY IONS MAGNESIUM COMPOUNDS MAGNESIUM OXIDES METHANATION NUMERICAL DATA ORGANIC COMPOUNDS ORGANOMETALLIC COMPOUNDS OSMIUM COMPLEXES Other techniques and industries OXIDES OXYGEN COMPOUNDS PH VALUE SORPTION SPECTRA SURFACE PROPERTIES Theory of reactions, general kinetics Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry TRANSITION ELEMENT COMPLEXES
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