Long-range photoinduced through-bond electron transfer and radiative recombination via rigid nonconjugated bridges: distance and solvent dependence

A series of molecules 1 was synthesized containing a 1,4-dimethoxynaphthalene donor (D) an a 1,1-dicyanoethylene acceptor (a) interconnected by five different, rigid, nonconjugated bridges. The length of the bridges varies with increments of two sigma-bonds from four in 1(4) to 12 sigma-bonds in 1(1...

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Veröffentlicht in:	J. Am. Chem. Soc.; (United States) 1987-05, Vol.109 (11), p.3258-3269
Hauptverfasser:	Oevering, Henk, Paddon-Row, Michael N, Heppener, Marc, Oliver, Anna M, Cotsaris, E, Verhoeven, Jan W, Hush, Noel S
Format:	Artikel
Sprache:	eng
Schlagworte:	400500 - Photochemistry ABSORPTION SPECTROSCOPY ACETATES ACETONITRILE ACTIVATION ENERGY ALKANES ALKENES AROMATICS BENZENE CARBOXYLIC ACID SALTS CHEMICAL PREPARATION CHEMICAL REACTION KINETICS CHEMICAL REACTIONS CHEMISTRY CONDENSED AROMATICS CYCLOALKANES CYCLOHEXANE DATA ELECTRON SPECTROSCOPY ELECTRON TRANSFER EMISSION SPECTROSCOPY ENERGY ENERGY LEVELS ETHERS Exact sciences and technology EXCITED STATES EXPERIMENTAL DATA FURANS General and physical chemistry HETEROCYCLIC COMPOUNDS HYDROCARBONS INFORMATION INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY KINETICS MOLECULAR STRUCTURE NAPHTHALENE NITRILES NUMERICAL DATA ORGANIC COMPOUNDS ORGANIC NITROGEN COMPOUNDS ORGANIC OXYGEN COMPOUNDS ORGANIC SOLVENTS PHOTOCHEMICAL REACTIONS PHOTOCHEMISTRY PHOTOELECTRON SPECTROSCOPY Physical chemistry of induced reactions (with radiations, particles and ultrasonics) REACTION KINETICS SOLVENT PROPERTIES SOLVENTS SPECTROSCOPY SYNTHESIS TETRAHYDROFURAN THERMODYNAMICS
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