Fluorinated Calix[4]pyrrole and Dipyrrolylquinoxaline:  Neutral Anion Receptors with Augmented Affinities and Enhanced Selectivities

The use of the 3,4-difluoro-1H-pyrrole as a building block for the preparation of octamethyloctafluorocalix[4]pyrrole and 2,3-di(3‘,4‘-difluoropyrrol-2‘yl)quinoxaline is described. These latter two entities act as neutral anion receptors and were found to bind anions such as fluoride, chloride, or d...

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Veröffentlicht in:Journal of the American Chemical Society 2000-10, Vol.122 (42), p.10268-10272
Hauptverfasser: Anzenbacher, Pavel, Try, Andrew C, Miyaji, Hidekazu, Jursíková, Karolina, Lynch, Vincent M, Marquez, Manuel, Sessler, Jonathan L
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Sprache:eng
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